Heterobimetallic (acac)2Co(ox)Ln(HBpz3)2 complexes: Synthesis, characterization and spectroscopic properties

Md Abdus Subhan, Takayuki Sanada, Takayoshi Suzuki, Sumio Kaizaki

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The syntheses and characterizations of a series of complexes, [(acac) 2Co(ox)Ln(HBpz3)2] (Co(ox)Ln, Ln=Sm to Lu) is reported here. Cobalt(III) complexes, Co(ox)Ln, have been compared with chromium(III) complexes, Cr(ox)Ln due to their analogous features in view of structure and spectroscopy. NIR CD spectrum of [(acac) 2Co(ox)Yb(HBpz3)2] is examined in comparison with that of the related complexes to reveal the stereospecific formation with configurational chirality around YbIII ion.

Original languageEnglish
Pages (from-to)263-268
Number of pages6
JournalInorganica Chimica Acta
Volume353
DOIs
Publication statusPublished - Sep 8 2003
Externally publishedYes

Keywords

  • Co(ox)Ln
  • Cobalt(III)
  • Configurational chirality
  • Heterobimetallic complexes
  • Lanthanide(III)
  • Stereospecific formation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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