Halofluorination of alkenes using tetrabutylammonium dihydrogentrifluoride

Manabu Kuroboshi; Tamejiro Hiyama

doi:10.1016/S0040-4039(00)92048-3

Halofluorination of alkenes using tetrabutylammonium dihydrogentrifluoride

Manabu Kuroboshi, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Regio-, stereo-, and chemoselective halofluorination of alkenes is achieved using N-haloamides and tetrabutylammonium dihydrogentrifluoride, and the resulting F-I adducts were successfully converted into fluoroalkenes under dehydroiodination with 1,8-diazabicyclo[5.4.0]undec-7-ene.

Original language	English
Pages (from-to)	1215-1218
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4039(00)92048-3
Publication status	Published - Feb 25 1991
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Halofluorination of alkenes using tetrabutylammonium dihydrogentrifluoride",

abstract = "Regio-, stereo-, and chemoselective halofluorination of alkenes is achieved using N-haloamides and tetrabutylammonium dihydrogentrifluoride, and the resulting F-I adducts were successfully converted into fluoroalkenes under dehydroiodination with 1,8-diazabicyclo[5.4.0]undec-7-ene.",

author = "Manabu Kuroboshi and Tamejiro Hiyama",

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AU - Hiyama, Tamejiro

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Y1 - 1991/2/25

N2 - Regio-, stereo-, and chemoselective halofluorination of alkenes is achieved using N-haloamides and tetrabutylammonium dihydrogentrifluoride, and the resulting F-I adducts were successfully converted into fluoroalkenes under dehydroiodination with 1,8-diazabicyclo[5.4.0]undec-7-ene.

AB - Regio-, stereo-, and chemoselective halofluorination of alkenes is achieved using N-haloamides and tetrabutylammonium dihydrogentrifluoride, and the resulting F-I adducts were successfully converted into fluoroalkenes under dehydroiodination with 1,8-diazabicyclo[5.4.0]undec-7-ene.

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Halofluorination of alkenes using tetrabutylammonium dihydrogentrifluoride

Abstract

ASJC Scopus subject areas

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