Graphene-based carbocatalysts for carbon-carbon bond formation

Muhammad Sohail Ahmad, Yuta Nishina

Research output: Contribution to journalReview article

Abstract

Organic transformations are usually catalyzed by metal-based catalysts. In contrast, metal-free catalysts have attracted considerable attention from the viewpoint of sustainability and safety. Among the studies in metal-free catalysis, graphene-based materials have been introduced in the reactions that are usually catalyzed by transition metal catalysts. This review covers the literature (up to the beginning of April 2020) on the use of graphene and its derivatives as carbocatalysts for C-C bond-forming reactions, which are one of the fundamental reactions in organic syntheses. Besides, mechanistic studies are included for the rational understanding of the catalysis. Graphene has significant potential in the field of metal-free catalysis because of the fine-tunable potential of the structure, high stability and durability, and no metal contamination, making it a next-generation candidate material in catalysis.

Original languageEnglish
Pages (from-to)12210-12227
Number of pages18
JournalNanoscale
Volume12
Issue number23
DOIs
Publication statusPublished - Jun 21 2020

ASJC Scopus subject areas

  • Materials Science(all)

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