Geometric selectivity, hydrogen-bonding interaction, and solvatochromism of Bis{N-(aminoalkyl)salicylamidato(2-)}cobaltate(III)

Ryoji Mitsuhashi, Takayoshi Suzuki, Yukinari Sunatsuki, Masaaki Kojima

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Abstract

Cobalt(III) complexes with N-(aminoalkyl)salicylamide dianions, Ln 2- (n = 14), have been prepared and their molecular and crystal structures have been determined. The geometric (mer- or fac-) selectivity of [Co(Ln)2]- complexes was dependent on the number of the amineamidato chelate ring member. Intermolecular homochiral hydrogen-bonds and solvatochromic behavior of the complexes were also observed.

Original languageEnglish
Pages (from-to)696-698
Number of pages3
JournalChemistry Letters
Volume40
Issue number7
DOIs
Publication statusPublished - Jun 24 2011

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ASJC Scopus subject areas

  • Chemistry(all)

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