Abstract
Two geometric isomers of [RuCl2(PPh3)2(O-N)]-type complex were prepared and characterized by X-ray crystallography (PPh3 = triphenylphosphine, O-N = Hpia/pia-, Hpia = 3-hydroxypicolinamide). The electrochemical properties of the complexes upon protonation/deprotonation were investigated. The redox potential of the Ru center was remarkably shifted by isomerization. The UV-vis and electrochemical measurements suggested that slow isomerization from trans(P,Cl),trans(P,N) geometry to trans(P,P) geometry induced the oxidation and deprotonation of the complex.
| Original language | English |
|---|---|
| Pages (from-to) | 479-482 |
| Number of pages | 4 |
| Journal | Chemistry Letters |
| Volume | 47 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Jan 1 2018 |
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Keywords
- Geometric isomerism
- Redox potential shift
- Ru(II/III) complex
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Geometric isomerism and redox properties of ruthenium(II/III) complexes with 3-hydroxypicolinamide. / Mitsuhashi, Ryoji; Suzuki, Takayoshi; Mikuriya, Masahiro.
In: Chemistry Letters, Vol. 47, No. 4, 01.01.2018, p. 479-482.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Geometric isomerism and redox properties of ruthenium(II/III) complexes with 3-hydroxypicolinamide
AU - Mitsuhashi, Ryoji
AU - Suzuki, Takayoshi
AU - Mikuriya, Masahiro
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Two geometric isomers of [RuCl2(PPh3)2(O-N)]-type complex were prepared and characterized by X-ray crystallography (PPh3 = triphenylphosphine, O-N = Hpia/pia-, Hpia = 3-hydroxypicolinamide). The electrochemical properties of the complexes upon protonation/deprotonation were investigated. The redox potential of the Ru center was remarkably shifted by isomerization. The UV-vis and electrochemical measurements suggested that slow isomerization from trans(P,Cl),trans(P,N) geometry to trans(P,P) geometry induced the oxidation and deprotonation of the complex.
AB - Two geometric isomers of [RuCl2(PPh3)2(O-N)]-type complex were prepared and characterized by X-ray crystallography (PPh3 = triphenylphosphine, O-N = Hpia/pia-, Hpia = 3-hydroxypicolinamide). The electrochemical properties of the complexes upon protonation/deprotonation were investigated. The redox potential of the Ru center was remarkably shifted by isomerization. The UV-vis and electrochemical measurements suggested that slow isomerization from trans(P,Cl),trans(P,N) geometry to trans(P,P) geometry induced the oxidation and deprotonation of the complex.
KW - Geometric isomerism
KW - Redox potential shift
KW - Ru(II/III) complex
UR - http://www.scopus.com/inward/record.url?scp=85044424367&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85044424367&partnerID=8YFLogxK
U2 - 10.1246/cl.171166
DO - 10.1246/cl.171166
M3 - Article
AN - SCOPUS:85044424367
VL - 47
SP - 479
EP - 482
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 4
ER -