Abstract
The "cation pools" of diarylcarbenium ions have been generated by the low-temperature electrochemical oxidation of diphenylmethane derivatives. In addition to diphenylmethanes having various substituents, 9,10-dihydroanthracene, dibenzosuberane, and xanthenes, which are annulated derivatives of diphenylmethane were also found to serve as a precursor of cation pools. The generation of the diarylcarbenium ion was confirmed by low-temperature NMR analysis and cold-spray mass analysis. Reactivity was also investigated by reactions with various carbon nucleophiles such as allyltrimethylsilane, 1,3,5-trimethylbenzene, and anisole.
| Original language | English |
|---|---|
| Pages (from-to) | 594-599 |
| Number of pages | 6 |
| Journal | Bulletin of the Chemical Society of Japan |
| Volume | 82 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 2009 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Generation of diarylcarbenium ion poolsviaelectrochemical C-H bond dissociation. / Okajima, Masayuki; Soga, Kazuya; Watanabe, Takashi; Terao, Kimitada; Nokami, Toshiki; Suga, Seiji; Yoshida, Jun Ichi.
In: Bulletin of the Chemical Society of Japan, Vol. 82, No. 5, 2009, p. 594-599.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Generation of diarylcarbenium ion poolsviaelectrochemical C-H bond dissociation
AU - Okajima, Masayuki
AU - Soga, Kazuya
AU - Watanabe, Takashi
AU - Terao, Kimitada
AU - Nokami, Toshiki
AU - Suga, Seiji
AU - Yoshida, Jun Ichi
PY - 2009
Y1 - 2009
N2 - The "cation pools" of diarylcarbenium ions have been generated by the low-temperature electrochemical oxidation of diphenylmethane derivatives. In addition to diphenylmethanes having various substituents, 9,10-dihydroanthracene, dibenzosuberane, and xanthenes, which are annulated derivatives of diphenylmethane were also found to serve as a precursor of cation pools. The generation of the diarylcarbenium ion was confirmed by low-temperature NMR analysis and cold-spray mass analysis. Reactivity was also investigated by reactions with various carbon nucleophiles such as allyltrimethylsilane, 1,3,5-trimethylbenzene, and anisole.
AB - The "cation pools" of diarylcarbenium ions have been generated by the low-temperature electrochemical oxidation of diphenylmethane derivatives. In addition to diphenylmethanes having various substituents, 9,10-dihydroanthracene, dibenzosuberane, and xanthenes, which are annulated derivatives of diphenylmethane were also found to serve as a precursor of cation pools. The generation of the diarylcarbenium ion was confirmed by low-temperature NMR analysis and cold-spray mass analysis. Reactivity was also investigated by reactions with various carbon nucleophiles such as allyltrimethylsilane, 1,3,5-trimethylbenzene, and anisole.
UR - http://www.scopus.com/inward/record.url?scp=67649311813&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=67649311813&partnerID=8YFLogxK
U2 - 10.1246/bcsj.82.594
DO - 10.1246/bcsj.82.594
M3 - Article
AN - SCOPUS:67649311813
VL - 82
SP - 594
EP - 599
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
SN - 0009-2673
IS - 5
ER -