Generation of diarylcarbenium ion poolsviaelectrochemical C-H bond dissociation

Masayuki Okajima; Kazuya Soga; Takashi Watanabe; Kimitada Terao; Toshiki Nokami; Seiji Suga; Jun Ichi Yoshida

doi:10.1246/bcsj.82.594

Generation of diarylcarbenium ion poolsviaelectrochemical C-H bond dissociation

Masayuki Okajima, Kazuya Soga, Takashi Watanabe, Kimitada Terao, Toshiki Nokami, Seiji Suga, Jun Ichi Yoshida

Research output: Contribution to journal › Article

27 Citations (Scopus)

Abstract

The "cation pools" of diarylcarbenium ions have been generated by the low-temperature electrochemical oxidation of diphenylmethane derivatives. In addition to diphenylmethanes having various substituents, 9,10-dihydroanthracene, dibenzosuberane, and xanthenes, which are annulated derivatives of diphenylmethane were also found to serve as a precursor of cation pools. The generation of the diarylcarbenium ion was confirmed by low-temperature NMR analysis and cold-spray mass analysis. Reactivity was also investigated by reactions with various carbon nucleophiles such as allyltrimethylsilane, 1,3,5-trimethylbenzene, and anisole.

Original language	English
Pages (from-to)	594-599
Number of pages	6
Journal	Bulletin of the Chemical Society of Japan
Volume	82
Issue number	5
DOIs	https://doi.org/10.1246/bcsj.82.594
Publication status	Published - Jul 1 2009
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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Okajima, M., Soga, K., Watanabe, T., Terao, K., Nokami, T., Suga, S., & Yoshida, J. I. (2009). Generation of diarylcarbenium ion poolsviaelectrochemical C-H bond dissociation. Bulletin of the Chemical Society of Japan, 82(5), 594-599. https://doi.org/10.1246/bcsj.82.594

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AU - Okajima, Masayuki

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AU - Watanabe, Takashi

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AU - Nokami, Toshiki

AU - Suga, Seiji

AU - Yoshida, Jun Ichi

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