Generation of α-boryl radicals by reduction of α-haloalkylboronic esters with CrCl2

Kazuhiko Takai, Norio Shinomiya, Masako Ohta

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Treatment of α-chloroalkylboronic esters with CrCl2 in the presence of LiI and TMEDA generates α-boryl radicals, which add to α,β-unsaturated esters in a 1,4-fashion under mild conditions in excellent yields.

Original languageEnglish
Pages (from-to)253-254
Number of pages2
JournalSynlett
Issue number3
Publication statusPublished - 1998

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Generation of α-boryl radicals by reduction of α-haloalkylboronic esters with CrCl2. / Takai, Kazuhiko; Shinomiya, Norio; Ohta, Masako.

In: Synlett, No. 3, 1998, p. 253-254.

Research output: Contribution to journalArticle

Takai, Kazuhiko ; Shinomiya, Norio ; Ohta, Masako. / Generation of α-boryl radicals by reduction of α-haloalkylboronic esters with CrCl2. In: Synlett. 1998 ; No. 3. pp. 253-254.
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