Generation of α-boryl radicals by reduction of α-haloalkylboronic esters with CrCl2

Kazuhiko Takai, Norio Shinomiya, Masako Ohta

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Treatment of α-chloroalkylboronic esters with CrCl2 in the presence of LiI and TMEDA generates α-boryl radicals, which add to α,β-unsaturated esters in a 1,4-fashion under mild conditions in excellent yields.

Original languageEnglish
Pages (from-to)253-254
Number of pages2
JournalSynlett
Issue number3
DOIs
Publication statusPublished - Jan 1 1998

ASJC Scopus subject areas

  • Organic Chemistry

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