Generation and Carbonyl Addition of Dibromofluoromethyllithium

Manabu Kuroboshi, Nobuko Yamada, Yoko Takebe, Tamejiro Hiyama

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

When CFBr3 was treated with n-BuLi at -130 °C, thermally labile LiCFBr2 was generated which reacted smoothly with a coexisting electrophile RR'CO to give an adduct RR'C(OH)CFBr2 in good yield.

Original languageEnglish
Pages (from-to)987-988
Number of pages2
JournalSynlett
Volume1995
Issue number9
DOIs
Publication statusPublished - Sep 1995

Keywords

  • carbenoid
  • carbonyl addition
  • fluorinated alcohol
  • halofluoromethane
  • halohydrin

ASJC Scopus subject areas

  • Organic Chemistry

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