Formation of the Pb-added Bi-2212 phase

Makoto Hayashi, Minoru Fukuhara, Akira Doi, Naoya Kobayashi, Yasunori Ikeda, Mikio Takano, Yoshichika Bando, Yoshihiro Kusano, Jun Takada

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1 Citation (Scopus)


The compositional range and the structure of the solid solution of the Pb-added 2212 phase has been studied in Bi2Sr3-xCaxCu2PbyOz heated in Ar at 795°C to 822°C. The monophasic compositional range increases as x decreases. For x=1.25 monophasic products with y⪳0.6 can be obtained. The structure symmetry changes from tetragonal in y⪳0.3 to orthorhombic in y≧0.4. The monophasic compositional range and the Pb-compositional dependence of the lattice parameters in the Pb-added 2212 phase are remarkably different from those in Bi2-yPbySr1.5Ca1.5Cu2Oz reported so far. Tc decreases as y increases.

Original languageEnglish
Pages (from-to)1492-1496
Number of pages5
JournalJournal of the Japan Society of Powder and Powder Metallurgy
Issue number12
Publication statusPublished - Feb 1 1994

ASJC Scopus subject areas

  • Mechanical Engineering
  • Industrial and Manufacturing Engineering
  • Metals and Alloys
  • Materials Chemistry


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