Formation of the High-tc Phase in Bi-2223 System in Various Atmospheres —Effect of o2-Partial Pressure—

Naoya Kobayashi, Minoru Fukuhara, Akira Doi, Toshio Takada, Yoshihiro Kusano, Jun Takada, Yasunori Ikeda, Mikio Takano

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The effects of O2-partial pressure on formation of the Bi-2223 phase. The samples were heated at 807°C∼850°C under various O2 atmospheres after calination in air or Ar flow. Single phase products of the 2223 phase were obtained by heating in 20%O2 both in Ar and air. The Pb-substituted 2212* phase, (Ca, Sr)2CuO3 and CuO coexist in samples calcined in Ar. The 2223 phase forms at a markedly lower temperature (807°C) in samples calcined in Ar than in those in air. In samples calcined in Ar the 2223 phase forms without formation of (Ca, Sr)2PbO4. These results reveal that the formation process of the 2223 phase in samples calcined in Ar is different from that in those in air.

Original languageEnglish
Pages (from-to)1053-1056
Number of pages4
JournalJournal of the Japan Society of Powder and Powder Metallurgy
Issue number11
Publication statusPublished - 1993

ASJC Scopus subject areas

  • Mechanical Engineering
  • Industrial and Manufacturing Engineering
  • Metals and Alloys
  • Materials Chemistry


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