Formation of cyclic and polymeric structures from Zwitterions

Harunobu Komatsu, Wataru Oi, Kazumasa Naritani, Kazuto Takaishi, Masanobu Uchiyama, Atsuya Muranaka, Hiromitsu Maeda

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Covalent linkages: Zwitterion-based covalent linkages were observed in cyclic oligomers and in dispersed polymers based on monomers. Addition of acids and bases promoted transitions between monomeric species and the oligomeric and/or polymeric states. Exchange of constituent monomer units in the cyclic oligomers was observed in the solution state, whereas the polymers obtained as precipitates from CH3CN were not converted to the cyclic oligomers (see scheme).

Original languageEnglish
Pages (from-to)6956-6960
Number of pages5
JournalChemistry - A European Journal
Volume19
Issue number22
DOIs
Publication statusPublished - May 27 2013
Externally publishedYes

Keywords

  • anions
  • cations
  • nanostructures
  • supramolecular chemistry
  • zwitterions

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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  • Cite this

    Komatsu, H., Oi, W., Naritani, K., Takaishi, K., Uchiyama, M., Muranaka, A., & Maeda, H. (2013). Formation of cyclic and polymeric structures from Zwitterions. Chemistry - A European Journal, 19(22), 6956-6960. https://doi.org/10.1002/chem.201300704