Formation of [Cu(η2-H2)]+ species in MFI-type zeolite and resulting H-D exchange reaction with hydrogen on Brønsted acid sites at 300 K

Yasushige Kuroda; Takae Okamoto; Toshinori Mori; Yuzo Yoshikawa

doi:10.1246/cl.2004.1580

Formation of [Cu(η²-H₂)]⁺ species in MFI-type zeolite and resulting H-D exchange reaction with hydrogen on Brønsted acid sites at 300 K

Yasushige Kuroda, Takae Okamoto, Toshinori Mori, Yuzo Yoshikawa

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

We examined the adsorption feature of the CuMFI sample for H₂ adsorption and found a specific interaction between Cu⁺ exchanged in MFI and H₂ even at 300 K, the formation of η²-type H₂-adsorbed species in MFI-type zeolite; it caused H-D exchange reaction with hydrogen on Brønsted acid sites even at 300 K.

Original language	English
Pages (from-to)	1580-1581
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	12
DOIs	https://doi.org/10.1246/cl.2004.1580
Publication status	Published - Dec 5 2004

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.2004.1580

Cite this

@article{884185fac3614830b7dbbf7f6942d1ed,

title = "Formation of [Cu(η2-H2)]+ species in MFI-type zeolite and resulting H-D exchange reaction with hydrogen on Br{\o}nsted acid sites at 300 K",

abstract = "We examined the adsorption feature of the CuMFI sample for H2 adsorption and found a specific interaction between Cu+ exchanged in MFI and H2 even at 300 K, the formation of η2-type H2-adsorbed species in MFI-type zeolite; it caused H-D exchange reaction with hydrogen on Br{\o}nsted acid sites even at 300 K.",

author = "Yasushige Kuroda and Takae Okamoto and Toshinori Mori and Yuzo Yoshikawa",

year = "2004",

month = dec,

day = "5",

doi = "10.1246/cl.2004.1580",

language = "English",

volume = "33",

pages = "1580--1581",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "12",

}

TY - JOUR

T1 - Formation of [Cu(η2-H2)]+ species in MFI-type zeolite and resulting H-D exchange reaction with hydrogen on Brønsted acid sites at 300 K

AU - Kuroda, Yasushige

AU - Okamoto, Takae

AU - Mori, Toshinori

AU - Yoshikawa, Yuzo

PY - 2004/12/5

Y1 - 2004/12/5

N2 - We examined the adsorption feature of the CuMFI sample for H2 adsorption and found a specific interaction between Cu+ exchanged in MFI and H2 even at 300 K, the formation of η2-type H2-adsorbed species in MFI-type zeolite; it caused H-D exchange reaction with hydrogen on Brønsted acid sites even at 300 K.

AB - We examined the adsorption feature of the CuMFI sample for H2 adsorption and found a specific interaction between Cu+ exchanged in MFI and H2 even at 300 K, the formation of η2-type H2-adsorbed species in MFI-type zeolite; it caused H-D exchange reaction with hydrogen on Brønsted acid sites even at 300 K.

UR - http://www.scopus.com/inward/record.url?scp=14844325340&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=14844325340&partnerID=8YFLogxK

U2 - 10.1246/cl.2004.1580

DO - 10.1246/cl.2004.1580

M3 - Article

AN - SCOPUS:14844325340

SN - 0366-7022

VL - 33

SP - 1580

EP - 1581

JO - Chemistry Letters

JF - Chemistry Letters

IS - 12

ER -

Formation of [Cu(η²-H₂)]⁺ species in MFI-type zeolite and resulting H-D exchange reaction with hydrogen on Brønsted acid sites at 300 K

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this