Fluoro-pummerer rearrangement under oxidative desulfurization fluorination conditions. facile synthesis of oligofluoroalkyl sulfides

Satoru Furuta; Manabu Kuroboshi; Tamejiro Hiyama

doi:10.1016/00404-0399(50)1768D-

Fluoro-pummerer rearrangement under oxidative desulfurization fluorination conditions. facile synthesis of oligofluoroalkyl sulfides

Satoru Furuta, Manabu Kuroboshi, Tamejiro Hiyama

Research output: Contribution to journal › Article

Abstract

Upon treatment with n-Bu₄NH₂F₃ and 1,3-dibromo-5,5-dimethylhydantoin, various organic sulfides were readily fluorinated to give α-fluoro sulfides. When (HF)₉-Py was used as the fluorinating agent, normal oxidative desulfurization fluorination occurred depending on the structure of the substrates.

Original language	English
Pages (from-to)	8243-8246
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	45
DOIs	https://doi.org/10.1016/00404-0399(50)1768D-
Publication status	Published - Nov 6 1995
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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Furuta, S., Kuroboshi, M., & Hiyama, T. (1995). Fluoro-pummerer rearrangement under oxidative desulfurization fluorination conditions. facile synthesis of oligofluoroalkyl sulfides. Tetrahedron Letters, 36(45), 8243-8246. https://doi.org/10.1016/00404-0399(50)1768D-

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abstract = "Upon treatment with n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin, various organic sulfides were readily fluorinated to give α-fluoro sulfides. When (HF)9-Py was used as the fluorinating agent, normal oxidative desulfurization fluorination occurred depending on the structure of the substrates.",

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AU - Hiyama, Tamejiro

PY - 1995/11/6

Y1 - 1995/11/6

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AB - Upon treatment with n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin, various organic sulfides were readily fluorinated to give α-fluoro sulfides. When (HF)9-Py was used as the fluorinating agent, normal oxidative desulfurization fluorination occurred depending on the structure of the substrates.

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