Fluoro-pummerer rearrangement under oxidative desulfurization fluorination conditions. facile synthesis of oligofluoroalkyl sulfides

Satoru Furuta, Manabu Kuroboshi, Tamejiro Hiyama

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Upon treatment with n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin, various organic sulfides were readily fluorinated to give α-fluoro sulfides. When (HF)9-Py was used as the fluorinating agent, normal oxidative desulfurization fluorination occurred depending on the structure of the substrates.

Original languageEnglish
Pages (from-to)8243-8246
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number45
DOIs
Publication statusPublished - Nov 6 1995
Externally publishedYes

Fingerprint

Fluorination
Halogenation
Sulfides
Desulfurization
Substrates
1,3-dibromo-5,5-dimethylhydantoin

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Fluoro-pummerer rearrangement under oxidative desulfurization fluorination conditions. facile synthesis of oligofluoroalkyl sulfides. / Furuta, Satoru; Kuroboshi, Manabu; Hiyama, Tamejiro.

In: Tetrahedron Letters, Vol. 36, No. 45, 06.11.1995, p. 8243-8246.

Research output: Contribution to journalArticle

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