Fluoride Complexation of Element 104, Rutherfordium

Hiromitsu Haba, Kazuaki Tsukada, Masato Asai, Atsushi Toyoshima, Kazuhiko Akiyama, Ichiro Nishinaka, Masaru Hirata, Tsuyoshi Yaita, Shin Ichi Ichikawa, Yuichiro Nagame, Ken Ichiro Yasuda, Yutaka Miyamoto, Tetsuya Kaneko, Shin Ichi Goto, Sawako Ono, Toshiyuki Hirai, Hisaaki Kudo, Mitsuru Shigekawa, Atsushi Shinohara, Yasuji OuraHiromichi Nakahara, Keisuke Sueki, Hidetoshi Kikunaga, Norikazu Kinoshita, Naoya Tsuruga, Akihiko Yokoyama, Minoru Sakama, Shuich Enomoto, Matthias Schädel, Willy Brüchle, Jens V. Kratz

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

Fluoride complexation of element 104, rutherfordium (Rf), produced in the 248Cm(18O,5n)261 Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the 18O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.

Original languageEnglish
Pages (from-to)5219-5224
Number of pages6
JournalJournal of the American Chemical Society
Volume126
Issue number16
DOIs
Publication statusPublished - Apr 28 2004
Externally publishedYes

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Complexation
Fluorides
Ion exchange
Negative ions
Hydrofluoric acid
Anions
Chromatography
Anion Exchange Resins
Hydrofluoric Acid
Resins
Adsorption
Atoms
Rutherfordium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Haba, H., Tsukada, K., Asai, M., Toyoshima, A., Akiyama, K., Nishinaka, I., ... Kratz, J. V. (2004). Fluoride Complexation of Element 104, Rutherfordium. Journal of the American Chemical Society, 126(16), 5219-5224. https://doi.org/10.1021/ja031824u

Fluoride Complexation of Element 104, Rutherfordium. / Haba, Hiromitsu; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Akiyama, Kazuhiko; Nishinaka, Ichiro; Hirata, Masaru; Yaita, Tsuyoshi; Ichikawa, Shin Ichi; Nagame, Yuichiro; Yasuda, Ken Ichiro; Miyamoto, Yutaka; Kaneko, Tetsuya; Goto, Shin Ichi; Ono, Sawako; Hirai, Toshiyuki; Kudo, Hisaaki; Shigekawa, Mitsuru; Shinohara, Atsushi; Oura, Yasuji; Nakahara, Hiromichi; Sueki, Keisuke; Kikunaga, Hidetoshi; Kinoshita, Norikazu; Tsuruga, Naoya; Yokoyama, Akihiko; Sakama, Minoru; Enomoto, Shuich; Schädel, Matthias; Brüchle, Willy; Kratz, Jens V.

In: Journal of the American Chemical Society, Vol. 126, No. 16, 28.04.2004, p. 5219-5224.

Research output: Contribution to journalArticle

Haba, H, Tsukada, K, Asai, M, Toyoshima, A, Akiyama, K, Nishinaka, I, Hirata, M, Yaita, T, Ichikawa, SI, Nagame, Y, Yasuda, KI, Miyamoto, Y, Kaneko, T, Goto, SI, Ono, S, Hirai, T, Kudo, H, Shigekawa, M, Shinohara, A, Oura, Y, Nakahara, H, Sueki, K, Kikunaga, H, Kinoshita, N, Tsuruga, N, Yokoyama, A, Sakama, M, Enomoto, S, Schädel, M, Brüchle, W & Kratz, JV 2004, 'Fluoride Complexation of Element 104, Rutherfordium', Journal of the American Chemical Society, vol. 126, no. 16, pp. 5219-5224. https://doi.org/10.1021/ja031824u
Haba H, Tsukada K, Asai M, Toyoshima A, Akiyama K, Nishinaka I et al. Fluoride Complexation of Element 104, Rutherfordium. Journal of the American Chemical Society. 2004 Apr 28;126(16):5219-5224. https://doi.org/10.1021/ja031824u
Haba, Hiromitsu ; Tsukada, Kazuaki ; Asai, Masato ; Toyoshima, Atsushi ; Akiyama, Kazuhiko ; Nishinaka, Ichiro ; Hirata, Masaru ; Yaita, Tsuyoshi ; Ichikawa, Shin Ichi ; Nagame, Yuichiro ; Yasuda, Ken Ichiro ; Miyamoto, Yutaka ; Kaneko, Tetsuya ; Goto, Shin Ichi ; Ono, Sawako ; Hirai, Toshiyuki ; Kudo, Hisaaki ; Shigekawa, Mitsuru ; Shinohara, Atsushi ; Oura, Yasuji ; Nakahara, Hiromichi ; Sueki, Keisuke ; Kikunaga, Hidetoshi ; Kinoshita, Norikazu ; Tsuruga, Naoya ; Yokoyama, Akihiko ; Sakama, Minoru ; Enomoto, Shuich ; Schädel, Matthias ; Brüchle, Willy ; Kratz, Jens V. / Fluoride Complexation of Element 104, Rutherfordium. In: Journal of the American Chemical Society. 2004 ; Vol. 126, No. 16. pp. 5219-5224.
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abstract = "Fluoride complexation of element 104, rutherfordium (Rf), produced in the 248Cm(18O,5n)261 Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the 18O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.",
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AU - Asai, Masato

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AU - Nishinaka, Ichiro

AU - Hirata, Masaru

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AU - Ichikawa, Shin Ichi

AU - Nagame, Yuichiro

AU - Yasuda, Ken Ichiro

AU - Miyamoto, Yutaka

AU - Kaneko, Tetsuya

AU - Goto, Shin Ichi

AU - Ono, Sawako

AU - Hirai, Toshiyuki

AU - Kudo, Hisaaki

AU - Shigekawa, Mitsuru

AU - Shinohara, Atsushi

AU - Oura, Yasuji

AU - Nakahara, Hiromichi

AU - Sueki, Keisuke

AU - Kikunaga, Hidetoshi

AU - Kinoshita, Norikazu

AU - Tsuruga, Naoya

AU - Yokoyama, Akihiko

AU - Sakama, Minoru

AU - Enomoto, Shuich

AU - Schädel, Matthias

AU - Brüchle, Willy

AU - Kratz, Jens V.

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