Flow Analysis of Hydrogen Peroxide with a Dye-Formation Reaction Catalyzed by an Ion-Exchange Resin Modified with Mn 3+ -Tetrakis(sulfophenyl)porphine

Masaki Mifune, Takashi Mukuno, Misato Tani, Akimasa Iwado, Junichi Odo, Noriko Motohashi, Yutaka Saito

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11 Citations (Scopus)

Abstract

The present flow analysis of hydrogen peroxide is based on a measurement of the absorbance of quinoid-dye formed by a following reaction (1) using an anion-exchange resin modified with manganese(III)-tetrakis(sulfophenyl)porphine (Mn- TSPP r ), which catalyzes the reaction (1), just like an immobilized peroxidase: 4-aminoantipyrine+4-chlorophenol+2H 2 O 2 Mn-TSPP r → quinoid dye+4H 2 O [reaction (1)]. Mn-TSPP r is more advantageous than immobilized peroxidase in terms of storage and stability for both temperature and moisture. The present facilitated method is satisfactory in reproducibility and sensitivity.

Original languageEnglish
Pages (from-to)519-522
Number of pages4
JournalAnalytical Sciences
Volume14
Issue number3
DOIs
Publication statusPublished - Jan 1 1998

Keywords

  • 4-aminoantipyrine
  • 4-chlorophenol
  • Anion-exchange resin modified with manganese(iii)-tetrakis(sulfophenyl)porphine
  • Flow injection analysis
  • Hydrogen peroxide

ASJC Scopus subject areas

  • Analytical Chemistry

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