Abstract
The interlayer distance of graphene oxide (GO) in a Pd/GO composite could be tuned using cationic surfactants. The distance becomes larger when a large surfactant is used. The catalytic activity in Heck reactions dramatically improved using the surfactant-modified Pd/GO catalyst. Substrate selectivity could also be improved by adjusting the size of the surfactant to increase accessibility of substrates to the active catalytic centre.
| Original language | English |
|---|---|
| Pages (from-to) | 59835-59838 |
| Number of pages | 4 |
| Journal | RSC Advances |
| Volume | 4 |
| Issue number | 104 |
| DOIs | |
| Publication status | Published - 2014 |
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ASJC Scopus subject areas
- Chemical Engineering(all)
- Chemistry(all)
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Fine tuning of the sheet distance of graphene oxide that affects the activity and substrate selectivity of a Pd/graphene oxide catalyst in the Heck reaction. / Saito, Akinori; Yamamoto, Shun Ichi; Nishina, Yuta.
In: RSC Advances, Vol. 4, No. 104, 2014, p. 59835-59838.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Fine tuning of the sheet distance of graphene oxide that affects the activity and substrate selectivity of a Pd/graphene oxide catalyst in the Heck reaction
AU - Saito, Akinori
AU - Yamamoto, Shun Ichi
AU - Nishina, Yuta
PY - 2014
Y1 - 2014
N2 - The interlayer distance of graphene oxide (GO) in a Pd/GO composite could be tuned using cationic surfactants. The distance becomes larger when a large surfactant is used. The catalytic activity in Heck reactions dramatically improved using the surfactant-modified Pd/GO catalyst. Substrate selectivity could also be improved by adjusting the size of the surfactant to increase accessibility of substrates to the active catalytic centre.
AB - The interlayer distance of graphene oxide (GO) in a Pd/GO composite could be tuned using cationic surfactants. The distance becomes larger when a large surfactant is used. The catalytic activity in Heck reactions dramatically improved using the surfactant-modified Pd/GO catalyst. Substrate selectivity could also be improved by adjusting the size of the surfactant to increase accessibility of substrates to the active catalytic centre.
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UR - http://www.scopus.com/inward/citedby.url?scp=84912035206&partnerID=8YFLogxK
U2 - 10.1039/c4ra10512e
DO - 10.1039/c4ra10512e
M3 - Article
AN - SCOPUS:84912035206
VL - 4
SP - 59835
EP - 59838
JO - RSC Advances
JF - RSC Advances
SN - 2046-2069
IS - 104
ER -