Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt(II) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand

Ryoji Mitsuhashi, Kasper S. Pedersen, Takaaki Ueda, Takayoshi Suzuki, Jesper Bendix, Masahiro Mikuriya

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A new cobalt(ii) complex bearing a pair of cobalt(iii) tris-chelate complexes as metalloligands was prepared. The CoII ion possesses an ideal trigonal antiprismatic geometry because of the intermolecular hydrogen-bonds between the metalloligands via counter anions. This complex exhibits slow magnetic relaxation under a dc field reminiscent of a single-molecule magnet behavior.

Original languageEnglish
Pages (from-to)8869-8872
Number of pages4
JournalChemical Communications
Volume54
Issue number64
DOIs
Publication statusPublished - Jan 1 2018

    Fingerprint

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this