Ferro- and antiferromagnetic interactions in face-sharing trioctahedral NiIIMnIINiII and NiIIFeIIINiII complexes with the same 1-5/2-1 spin system

Tamami Kobayashi; Tomoka Yamaguchi; Hiromi Ohta; Yukinari Sunatsuki; Masaaki Kojima; Nazzareno Re; Matsuo Nonoyama; Naohide Matsumoto

doi:10.1039/b517503h

Ferro- and antiferromagnetic interactions in face-sharing trioctahedral Ni^IIMn^IINi^II and Ni^IIFe^IIINi^II complexes with the same 1-5/2-1 spin system

Tamami Kobayashi, Tomoka Yamaguchi, Hiromi Ohta, Yukinari Sunatsuki, Masaaki Kojima, Nazzareno Re, Matsuo Nonoyama, Naohide Matsumoto

Advanced Science Research Center

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

Two heterotrinuclear complexes, [Mn^II(Ni^IIL)₂]·2CH₃OH (where H₃L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [Fe^III(Ni^IIL)₂]NO₃·C ₂H₅OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (Ni^II-Mn^II) and antiferromagnetic (Ni^II-Fe^III).

Original language	English
Pages (from-to)	1950-1952
Number of pages	3
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b517503h
Publication status	Published - Jan 1 2006

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Kobayashi, T., Yamaguchi, T., Ohta, H., Sunatsuki, Y., Kojima, M., Re, N., Nonoyama, M., & Matsumoto, N. (2006). Ferro- and antiferromagnetic interactions in face-sharing trioctahedral Ni^IIMn^IINi^II and Ni^IIFe^IIINi^II complexes with the same 1-5/2-1 spin system. Chemical Communications, (18), 1950-1952. https://doi.org/10.1039/b517503h

Ferro- and antiferromagnetic interactions in face-sharing trioctahedral Ni^IIMn^IINi^II and Ni^IIFe^IIINi^II complexes with the same 1-5/2-1 spin system. / Kobayashi, Tamami; Yamaguchi, Tomoka; Ohta, Hiromi; Sunatsuki, Yukinari; Kojima, Masaaki; Re, Nazzareno; Nonoyama, Matsuo; Matsumoto, Naohide.

In: Chemical Communications, No. 18, 01.01.2006, p. 1950-1952.

Research output: Contribution to journal › Article

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abstract = "Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).",

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AU - Kobayashi, Tamami

AU - Yamaguchi, Tomoka

AU - Ohta, Hiromi

AU - Sunatsuki, Yukinari

AU - Kojima, Masaaki

AU - Re, Nazzareno

AU - Nonoyama, Matsuo

AU - Matsumoto, Naohide

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AB - Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).

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