Abstract
Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).
Original language | English |
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Pages (from-to) | 1950-1952 |
Number of pages | 3 |
Journal | Chemical Communications |
Issue number | 18 |
DOIs | |
Publication status | Published - Jan 1 2006 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry