Ferro- and antiferromagnetic interactions in face-sharing trioctahedral NiIIMnIINiII and NiIIFeIIINiII complexes with the same 1-5/2-1 spin system

Tamami Kobayashi; Tomoka Yamaguchi; Hiromi Ohta; Yukinari Sunatsuki; Masaaki Kojima; Nazzareno Re; Matsuo Nonoyama; Naohide Matsumoto

doi:10.1039/b517503h

Ferro- and antiferromagnetic interactions in face-sharing trioctahedral Ni^IIMn^IINi^II and Ni^IIFe^IIINi^II complexes with the same 1-5/2-1 spin system

Tamami Kobayashi, Tomoka Yamaguchi, Hiromi Ohta, Yukinari Sunatsuki, Masaaki Kojima, Nazzareno Re, Matsuo Nonoyama, Naohide Matsumoto

Advanced Science Research Center

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28 Citations (Scopus)

Abstract

Two heterotrinuclear complexes, [Mn^II(Ni^IIL)₂]·2CH₃OH (where H₃L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [Fe^III(Ni^IIL)₂]NO₃·C ₂H₅OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (Ni^II-Mn^II) and antiferromagnetic (Ni^II-Fe^III).

Original language	English
Pages (from-to)	1950-1952
Number of pages	3
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b517503h
Publication status	Published - Jan 1 2006

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Ferro- and antiferromagnetic interactions in face-sharing trioctahedral NiIIMnIINiII and NiIIFeIIINiII complexes with the same 1-5/2-1 spin system",

abstract = "Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).",

author = "Tamami Kobayashi and Tomoka Yamaguchi and Hiromi Ohta and Yukinari Sunatsuki and Masaaki Kojima and Nazzareno Re and Matsuo Nonoyama and Naohide Matsumoto",

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doi = "10.1039/b517503h",

language = "English",

pages = "1950--1952",

journal = "Chemical Communications",

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T1 - Ferro- and antiferromagnetic interactions in face-sharing trioctahedral NiIIMnIINiII and NiIIFeIIINiII complexes with the same 1-5/2-1 spin system

AU - Kobayashi, Tamami

AU - Yamaguchi, Tomoka

AU - Ohta, Hiromi

AU - Sunatsuki, Yukinari

AU - Kojima, Masaaki

AU - Re, Nazzareno

AU - Nonoyama, Matsuo

AU - Matsumoto, Naohide

PY - 2006/1/1

Y1 - 2006/1/1

N2 - Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).

AB - Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).

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Ferro- and antiferromagnetic interactions in face-sharing trioctahedral Ni^IIMn^IINi^II and Ni^IIFe^IIINi^II complexes with the same 1-5/2-1 spin system

Abstract

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