Ferro- and antiferromagnetic interactions in face-sharing trioctahedral NiIIMnIINiII and NiIIFeIIINiII complexes with the same 1-5/2-1 spin system

Tamami Kobayashi, Tomoka Yamaguchi, Hiromi Ohta, Yukinari Sunatsuki, Masaaki Kojima, Nazzareno Re, Matsuo Nonoyama, Naohide Matsumoto

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Abstract

Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).

Original languageEnglish
Pages (from-to)1950-1952
Number of pages3
JournalChemical Communications
Issue number18
DOIs
Publication statusPublished - 2006

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Metal ions

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Ferro- and antiferromagnetic interactions in face-sharing trioctahedral NiIIMnIINiII and NiIIFeIIINiII complexes with the same 1-5/2-1 spin system. / Kobayashi, Tamami; Yamaguchi, Tomoka; Ohta, Hiromi; Sunatsuki, Yukinari; Kojima, Masaaki; Re, Nazzareno; Nonoyama, Matsuo; Matsumoto, Naohide.

In: Chemical Communications, No. 18, 2006, p. 1950-1952.

Research output: Contribution to journalArticle

Kobayashi, Tamami ; Yamaguchi, Tomoka ; Ohta, Hiromi ; Sunatsuki, Yukinari ; Kojima, Masaaki ; Re, Nazzareno ; Nonoyama, Matsuo ; Matsumoto, Naohide. / Ferro- and antiferromagnetic interactions in face-sharing trioctahedral NiIIMnIINiII and NiIIFeIIINiII complexes with the same 1-5/2-1 spin system. In: Chemical Communications. 2006 ; No. 18. pp. 1950-1952.
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abstract = "Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).",
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AU - Kobayashi, Tamami

AU - Yamaguchi, Tomoka

AU - Ohta, Hiromi

AU - Sunatsuki, Yukinari

AU - Kojima, Masaaki

AU - Re, Nazzareno

AU - Nonoyama, Matsuo

AU - Matsumoto, Naohide

PY - 2006

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AB - Two heterotrinuclear complexes, [MnII(NiIIL)2]·2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [FeIII(NiIIL)2]NO3·C 2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (NiII-MnII) and antiferromagnetic (NiII-FeIII).

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