Facile transformation of 1-substituted F-1-alkenyl phosphates into polyfluorinated 1,3-dienes by use of phosphonium ylides

Yoshiji Okada, Manabu Kuroboshi, Takashi Ishihara

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

1-Substituted F-1-alkenyl phosphates, easily prepared from F-alkyl ketones and the sodium salt of diethyl phosphite, were allowed to react with various phosphonium ylides in tetrahydrofuran or hexane at room temperature or at the reflux temperature of the solvent to lead to the corresponding polyfluorinated 1,3-diene derivatives in moderate to good yields.

Original languageEnglish
Pages (from-to)435-438
Number of pages4
JournalJournal of Fluorine Chemistry
Volume41
Issue number3
DOIs
Publication statusPublished - 1988
Externally publishedYes

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dienes
tetrahydrofuran
ketones
phosphates
Phosphates
sodium
phosphate
Phosphites
salts
Temperature
Hexanes
room temperature
ketone
Hexane
Ketones
Salts
temperature
Sodium
salt
Derivatives

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Facile transformation of 1-substituted F-1-alkenyl phosphates into polyfluorinated 1,3-dienes by use of phosphonium ylides. / Okada, Yoshiji; Kuroboshi, Manabu; Ishihara, Takashi.

In: Journal of Fluorine Chemistry, Vol. 41, No. 3, 1988, p. 435-438.

Research output: Contribution to journalArticle

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AU - Ishihara, Takashi

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