Facile transformation of 1-substituted F-1-alkenyl phosphates into polyfluorinated 1,3-dienes by use of phosphonium ylides

Yoshiji Okada, Manabu Kuroboshi, Takashi Ishihara

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

1-Substituted F-1-alkenyl phosphates, easily prepared from F-alkyl ketones and the sodium salt of diethyl phosphite, were allowed to react with various phosphonium ylides in tetrahydrofuran or hexane at room temperature or at the reflux temperature of the solvent to lead to the corresponding polyfluorinated 1,3-diene derivatives in moderate to good yields.

Original languageEnglish
Pages (from-to)435-438
Number of pages4
JournalJournal of Fluorine Chemistry
Volume41
Issue number3
DOIs
Publication statusPublished - Dec 1988
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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