Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel-Crafts Acylation and Their Fundamental Properties

Koichi Mitsudo, Takashi Murakami, Takuya Shibasaki, Tomohiro Inada, Hiroki Mandai, Hiromi Ota, Seiji Suga

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Facile synthetic methods for constructing naphthothiophenone and its π-extended derivatives were developed. Naphthothiophenone and anthradithiophenedione were synthesized by the S-acylation of thiol to form chlorothioformate and subsequent Friedel-Crafts acylation. A bromination reaction of naphthothiophenone and its application to Suzuki-Miyaura cross-coupling was also carried out. The fundamental physical properties of these compounds were also investigated.

Original languageEnglish
Article numberst-2016-u0327-l
Pages (from-to)2327-2332
Number of pages6
JournalSynlett
Volume27
Issue number16
DOIs
Publication statusPublished - Oct 4 2016

Keywords

  • acylation
  • anthradithiophenedione
  • cross-coupling
  • naphthothiophenone
  • thiophenone

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel-Crafts Acylation and Their Fundamental Properties'. Together they form a unique fingerprint.

  • Cite this