Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel–Crafts Acylation and Their Fundamental Properties

Koichi Mitsudo, Takashi Murakami, Takuya Shibasaki, Tomohiro Inada, Hiroki Mandai, Hiromi Ota, Seiji Suga

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

Facile synthetic methods for constructing naphthothiophenone and its π-extended derivatives were developed. Naphthothiophenone and anthradithiophenedione were synthesized by the S-acylation of thiol to form chlorothioformate and subsequent Friedel–Crafts acylation. A bromination reaction of naphthothiophenone and its application to Suzuki–Miyaura cross-coupling was also carried out. The fundamental physical properties of these compounds were also investigated.

Original languageEnglish
JournalSynlett
DOIs
Publication statusAccepted/In press - Jun 14 2016

Fingerprint

Acylation
Derivatives
Sulfhydryl Compounds
Physical properties

Keywords

  • acylation
  • anthradithiophenedione
  • cross-coupling
  • naphthothiophenone
  • thiophenone

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel–Crafts Acylation and Their Fundamental Properties. / Mitsudo, Koichi; Murakami, Takashi; Shibasaki, Takuya; Inada, Tomohiro; Mandai, Hiroki; Ota, Hiromi; Suga, Seiji.

In: Synlett, 14.06.2016.

Research output: Contribution to journal › Article

Mitsudo, K, Murakami, T, Shibasaki, T, Inada, T, Mandai, H, Ota, H & Suga, S 2016, 'Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel–Crafts Acylation and Their Fundamental Properties', Synlett. https://doi.org/10.1055/s-0035-1562470
Mitsudo K, Murakami T, Shibasaki T, Inada T, Mandai H, Ota H et al. Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel–Crafts Acylation and Their Fundamental Properties. Synlett. 2016 Jun 14. https://doi.org/10.1055/s-0035-1562470
Mitsudo, Koichi ; Murakami, Takashi ; Shibasaki, Takuya ; Inada, Tomohiro ; Mandai, Hiroki ; Ota, Hiromi ; Suga, Seiji. / Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel–Crafts Acylation and Their Fundamental Properties. In: Synlett. 2016.
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