Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel-Crafts Acylation and Their Fundamental Properties

Koichi Mitsudo; Takashi Murakami; Takuya Shibasaki; Tomohiro Inada; Hiroki Mandai; Hiromi Ota; Seiji Suga

doi:10.1055/s-0035-1562470

Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel-Crafts Acylation and Their Fundamental Properties

Koichi Mitsudo, Takashi Murakami, Takuya Shibasaki, Tomohiro Inada, Hiroki Mandai, Hiromi Ota, Seiji Suga

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Facile synthetic methods for constructing naphthothiophenone and its π-extended derivatives were developed. Naphthothiophenone and anthradithiophenedione were synthesized by the S-acylation of thiol to form chlorothioformate and subsequent Friedel-Crafts acylation. A bromination reaction of naphthothiophenone and its application to Suzuki-Miyaura cross-coupling was also carried out. The fundamental physical properties of these compounds were also investigated.

Original language	English
Article number	st-2016-u0327-l
Pages (from-to)	2327-2332
Number of pages	6
Journal	Synlett
Volume	27
Issue number	16
DOIs	https://doi.org/10.1055/s-0035-1562470
Publication status	Published - Oct 4 2016

Keywords

acylation
anthradithiophenedione
cross-coupling
naphthothiophenone
thiophenone

ASJC Scopus subject areas

Organic Chemistry

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Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel-Crafts Acylation and Their Fundamental Properties. / Mitsudo, Koichi; Murakami, Takashi; Shibasaki, Takuya; Inada, Tomohiro; Mandai, Hiroki; Ota, Hiromi; Suga, Seiji.

In: Synlett, Vol. 27, No. 16, st-2016-u0327-l, 04.10.2016, p. 2327-2332.

Research output: Contribution to journal › Article › peer-review

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