Fabrication of novel core-shell microspheres consisting of single-walled carbon nanotubes and CaCO 3 through biomimetic mineralization

Tomoyuki Tajima, Akira Tsutsui, Tatsuo Fujii, Jun Takada, Yutaka Takaguchi

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Calcium carbonate (CaCO 3) in the presence of single-walled carbon nanotube (SWCNT) /fullerodendron supramolecular nanocomposites was crystallized with a CO 2 diffusion method under ambient conditions and in aqueous environments to produce monodisperse spherical SWCNT/CaCO 3 hybrids with a core-shell structure. The crystals nucleate at the carboxyl groups on the surface of the SWCNT/fullerodendron supramolecular nanocomposites grow around a spherical scaffold consisting of the SWCNTs, and finally form spherical calcite crystals embedded with and covered by the SWCNTs. Owing to of the phase transition from vaterite to calcite through a solvent-mediated process, the morphology of the microspheres is unique; the shell is primarily composed of calcite crystals of CaCO 3, and a greater amount of SWCNTs is embedded in the core moiety.

Original languageEnglish
Pages (from-to)620-624
Number of pages5
JournalPolymer Journal
Volume44
Issue number6
DOIs
Publication statusPublished - Jun 2012

Fingerprint

Calcium Carbonate
Calcite
Biomimetics
Single-walled carbon nanotubes (SWCN)
Microspheres
Fabrication
Crystals
Nanocomposites
Forms (concrete)
Calcium carbonate
Scaffolds
Phase transitions
Carbon Monoxide

Keywords

  • Biomineralization
  • Calcium carbonate
  • Carbon nanotubes
  • Core-shell structure
  • Dendrimer
  • Fullerene
  • Nanohybrid

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

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title = "Fabrication of novel core-shell microspheres consisting of single-walled carbon nanotubes and CaCO 3 through biomimetic mineralization",
abstract = "Calcium carbonate (CaCO 3) in the presence of single-walled carbon nanotube (SWCNT) /fullerodendron supramolecular nanocomposites was crystallized with a CO 2 diffusion method under ambient conditions and in aqueous environments to produce monodisperse spherical SWCNT/CaCO 3 hybrids with a core-shell structure. The crystals nucleate at the carboxyl groups on the surface of the SWCNT/fullerodendron supramolecular nanocomposites grow around a spherical scaffold consisting of the SWCNTs, and finally form spherical calcite crystals embedded with and covered by the SWCNTs. Owing to of the phase transition from vaterite to calcite through a solvent-mediated process, the morphology of the microspheres is unique; the shell is primarily composed of calcite crystals of CaCO 3, and a greater amount of SWCNTs is embedded in the core moiety.",
keywords = "Biomineralization, Calcium carbonate, Carbon nanotubes, Core-shell structure, Dendrimer, Fullerene, Nanohybrid",
author = "Tomoyuki Tajima and Akira Tsutsui and Tatsuo Fujii and Jun Takada and Yutaka Takaguchi",
year = "2012",
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T1 - Fabrication of novel core-shell microspheres consisting of single-walled carbon nanotubes and CaCO 3 through biomimetic mineralization

AU - Tajima, Tomoyuki

AU - Tsutsui, Akira

AU - Fujii, Tatsuo

AU - Takada, Jun

AU - Takaguchi, Yutaka

PY - 2012/6

Y1 - 2012/6

N2 - Calcium carbonate (CaCO 3) in the presence of single-walled carbon nanotube (SWCNT) /fullerodendron supramolecular nanocomposites was crystallized with a CO 2 diffusion method under ambient conditions and in aqueous environments to produce monodisperse spherical SWCNT/CaCO 3 hybrids with a core-shell structure. The crystals nucleate at the carboxyl groups on the surface of the SWCNT/fullerodendron supramolecular nanocomposites grow around a spherical scaffold consisting of the SWCNTs, and finally form spherical calcite crystals embedded with and covered by the SWCNTs. Owing to of the phase transition from vaterite to calcite through a solvent-mediated process, the morphology of the microspheres is unique; the shell is primarily composed of calcite crystals of CaCO 3, and a greater amount of SWCNTs is embedded in the core moiety.

AB - Calcium carbonate (CaCO 3) in the presence of single-walled carbon nanotube (SWCNT) /fullerodendron supramolecular nanocomposites was crystallized with a CO 2 diffusion method under ambient conditions and in aqueous environments to produce monodisperse spherical SWCNT/CaCO 3 hybrids with a core-shell structure. The crystals nucleate at the carboxyl groups on the surface of the SWCNT/fullerodendron supramolecular nanocomposites grow around a spherical scaffold consisting of the SWCNTs, and finally form spherical calcite crystals embedded with and covered by the SWCNTs. Owing to of the phase transition from vaterite to calcite through a solvent-mediated process, the morphology of the microspheres is unique; the shell is primarily composed of calcite crystals of CaCO 3, and a greater amount of SWCNTs is embedded in the core moiety.

KW - Biomineralization

KW - Calcium carbonate

KW - Carbon nanotubes

KW - Core-shell structure

KW - Dendrimer

KW - Fullerene

KW - Nanohybrid

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JF - Polymer Journal

SN - 0032-3896

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