Fabrication of metal nanoparticles from metal-filled carbon nanofibers and their size control by heating

T. Tokunaga, T. Kanematsu, T. Ota, K. Sasaki, T. Yamamoto, Yasuhiko Hayashi

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

In situ environmental transmission electron microscopy (ETEM) observation was used to reveal Sn inside Sn-filled carbon nanofibers (CNFs) during heating. Before and during heating, the Sn was covered completely by CNFs. The volume of Sn present in the Sn-filled CNFs gradually decreased during heating, with new Sn particles appearing at the top of the Sn-filled CNFs. It is thought that Sn diffused out of the Sn-filled CNFs and into the carbon wall of the metal-filled CNFs (MFCNFs). The specific surface area at the top of Sn-filled CNFs is higher specific surface than that at other parts and the temperature at the top of the MFCNF is lower than that at other parts; therefore, diffused Sn particles were formed at only the top of the Sn-filled CNF. Fabrication of Sn metal particles was tried by heating the Sn-filled CNFs, and it was clear that the metal particle size could be controlled by controlling the heating time.

Original languageEnglish
Title of host publicationIEEE Nanotechnology Materials and Devices Conference, IEEE NMDC 2013
PublisherIEEE Computer Society
Pages5-8
Number of pages4
ISBN (Print)9781479933877
DOIs
Publication statusPublished - 2013
Event2013 IEEE 8th Nanotechnology Materials and Devices Conference, IEEE NMDC 2013 - Tainan, Taiwan, Province of China
Duration: Oct 6 2013Oct 9 2013

Other

Other2013 IEEE 8th Nanotechnology Materials and Devices Conference, IEEE NMDC 2013
CountryTaiwan, Province of China
CityTainan
Period10/6/1310/9/13

Fingerprint

Carbon nanofibers
Metal nanoparticles
Heating
Fabrication
Metals
Specific surface area
Particle size
Transmission electron microscopy
Carbon

ASJC Scopus subject areas

  • Mechanics of Materials

Cite this

Tokunaga, T., Kanematsu, T., Ota, T., Sasaki, K., Yamamoto, T., & Hayashi, Y. (2013). Fabrication of metal nanoparticles from metal-filled carbon nanofibers and their size control by heating. In IEEE Nanotechnology Materials and Devices Conference, IEEE NMDC 2013 (pp. 5-8). [6707468] IEEE Computer Society. https://doi.org/10.1109/NMDC.2013.6707468

Fabrication of metal nanoparticles from metal-filled carbon nanofibers and their size control by heating. / Tokunaga, T.; Kanematsu, T.; Ota, T.; Sasaki, K.; Yamamoto, T.; Hayashi, Yasuhiko.

IEEE Nanotechnology Materials and Devices Conference, IEEE NMDC 2013. IEEE Computer Society, 2013. p. 5-8 6707468.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Tokunaga, T, Kanematsu, T, Ota, T, Sasaki, K, Yamamoto, T & Hayashi, Y 2013, Fabrication of metal nanoparticles from metal-filled carbon nanofibers and their size control by heating. in IEEE Nanotechnology Materials and Devices Conference, IEEE NMDC 2013., 6707468, IEEE Computer Society, pp. 5-8, 2013 IEEE 8th Nanotechnology Materials and Devices Conference, IEEE NMDC 2013, Tainan, Taiwan, Province of China, 10/6/13. https://doi.org/10.1109/NMDC.2013.6707468
Tokunaga T, Kanematsu T, Ota T, Sasaki K, Yamamoto T, Hayashi Y. Fabrication of metal nanoparticles from metal-filled carbon nanofibers and their size control by heating. In IEEE Nanotechnology Materials and Devices Conference, IEEE NMDC 2013. IEEE Computer Society. 2013. p. 5-8. 6707468 https://doi.org/10.1109/NMDC.2013.6707468
Tokunaga, T. ; Kanematsu, T. ; Ota, T. ; Sasaki, K. ; Yamamoto, T. ; Hayashi, Yasuhiko. / Fabrication of metal nanoparticles from metal-filled carbon nanofibers and their size control by heating. IEEE Nanotechnology Materials and Devices Conference, IEEE NMDC 2013. IEEE Computer Society, 2013. pp. 5-8
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abstract = "In situ environmental transmission electron microscopy (ETEM) observation was used to reveal Sn inside Sn-filled carbon nanofibers (CNFs) during heating. Before and during heating, the Sn was covered completely by CNFs. The volume of Sn present in the Sn-filled CNFs gradually decreased during heating, with new Sn particles appearing at the top of the Sn-filled CNFs. It is thought that Sn diffused out of the Sn-filled CNFs and into the carbon wall of the metal-filled CNFs (MFCNFs). The specific surface area at the top of Sn-filled CNFs is higher specific surface than that at other parts and the temperature at the top of the MFCNF is lower than that at other parts; therefore, diffused Sn particles were formed at only the top of the Sn-filled CNF. Fabrication of Sn metal particles was tried by heating the Sn-filled CNFs, and it was clear that the metal particle size could be controlled by controlling the heating time.",
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