Experimental analysis and numerical simulation for biodegradability of polyethylene

Fusako Kawai, Masaji Watanabe, Masaru Shibata, Shigeo Yokoyama, Yasuhiro Sudate

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Biodegradability of polyethylene wax (PEwax) was studied both experimentally and analytically. The weight loss of PEwax (0.5%) by a microbial consortium in approximately 3 weeks was 31.5% and the top molecular weights shifted to higher values. One of the features observed experimentally was fast consumption of low molecular weight-PEwax. On the other hand, one may speculate, theoretically, that hydrocarbons such as PE should be subject to an initial oxidation to yield carboxylated compounds at their terminals, which are then depolymerized via β-oxidation process. A mathematical model based on these theoretical and experimental aspects is proposed and a method of analysis is illustrated. β-Oxidation rates and consumption rates of low molecular weight-PEwax are determined numerically, and the temporal change of weight distribution is simulated. Numerical results are compared with experimental results, and the governing mechanism of biodegradation is interpreted. We conclude that the primary factors in biodegradation of polyethylene are an initial oxidation at the terminals of molecules followed by β-oxidation and consumption of low molecular weight-PEwax. The most reliable biodegradation limit was approx.

Original languageEnglish
Pages (from-to)129-135
Number of pages7
JournalPolymer Degradation and Stability
Volume76
Issue number1
DOIs
Publication statusPublished - Mar 11 2002

Keywords

  • Biodegradability
  • Numerical simulation
  • Polyethylene
  • Terminal oxidation
  • β-Oxidation

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Mechanics of Materials
  • Polymers and Plastics
  • Materials Chemistry

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