EXAFS Study on the Phase Transition (Phase α′ - δ ) in CH3NH3I

Hiroyuki Ishida, Hironobu Maeda, Akiko Hirano, Tamotsu Fujimoto, Yoshihiro Kubozono, Setsuo Kashino, Shuichi Emura

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

The local structure of CH3NH3I around the I-ion in Phase a ' and 5 was studied by iodine K-edge EXAFS. The crystal structure in Phase α ' was redetermined by single crystal X-ray diffraction. The Debye-Waller factor σ(2)derived from EXAFS spectra shows an anomalous behavior around the order-disorder transition temperature from Phase 5 to α'. The phase transition has been interpreted as the disordering process which involves not only the H atoms but also the C atoms in the cation.

Original languageEnglish
Pages (from-to)876-880
Number of pages5
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume50
Issue number9
DOIs
Publication statusPublished - Sep 1 1995

Fingerprint

Phase Transition
Phase transitions
Atoms
Order disorder transitions
Iodine
iodine
atoms
Cations
Crystal structure
transition temperature
Local Structure
Crystal Structure
Single crystals
disorders
Ions
Single Crystal
X-ray Diffraction
cations
X ray diffraction
crystal structure

Keywords

  • Crystal structure
  • EXAFS
  • Phase transition
  • X-ray diffraction

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Mathematical Physics
  • Physics and Astronomy(all)

Cite this

EXAFS Study on the Phase Transition (Phase α′ - δ ) in CH3NH3I. / Ishida, Hiroyuki; Maeda, Hironobu; Hirano, Akiko; Fujimoto, Tamotsu; Kubozono, Yoshihiro; Kashino, Setsuo; Emura, Shuichi.

In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Vol. 50, No. 9, 01.09.1995, p. 876-880.

Research output: Contribution to journal › Article

Ishida, H, Maeda, H, Hirano, A, Fujimoto, T, Kubozono, Y, Kashino, S & Emura, S 1995, 'EXAFS Study on the Phase Transition (Phase α′ - δ ) in CH3NH3I', Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, vol. 50, no. 9, pp. 876-880. https://doi.org/10.1515/zna-1995-0914
Ishida H, Maeda H, Hirano A, Fujimoto T, Kubozono Y, Kashino S et al. EXAFS Study on the Phase Transition (Phase α′ - δ ) in CH3NH3I. Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. 1995 Sep 1;50(9):876-880. https://doi.org/10.1515/zna-1995-0914
Ishida, Hiroyuki ; Maeda, Hironobu ; Hirano, Akiko ; Fujimoto, Tamotsu ; Kubozono, Yoshihiro ; Kashino, Setsuo ; Emura, Shuichi. / EXAFS Study on the Phase Transition (Phase α′ - δ ) in CH3NH3I. In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. 1995 ; Vol. 50, No. 9. pp. 876-880.
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