Evidence of an inversion mechanism for the thermal cis-trans isomerization of push-pull azobenzenes. A volumetric study

Norio Nishimura; Tohru Tanaka; Yoshimi Sueishi

doi:10.1039/C39850000903

Evidence of an inversion mechanism for the thermal cis-trans isomerization of push-pull azobenzenes. A volumetric study

Norio Nishimura, Tohru Tanaka, Yoshimi Sueishi

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8 Citations (Scopus)

Abstract

The partial molar volumes of trans-4-dimethylamino-4′-nitroazobenzene in solvents of different polarities are linearly related to the activation volumes in the same solvents for the thermal cis-trans isomerization of this species, which affords unequivocal evidence for an inversion transition state.

Original language	English
Pages (from-to)	903-904
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39850000903
Publication status	Published - Jan 1 1985

ASJC Scopus subject areas

Molecular Medicine

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title = "Evidence of an inversion mechanism for the thermal cis-trans isomerization of push-pull azobenzenes. A volumetric study",

abstract = "The partial molar volumes of trans-4-dimethylamino-4′-nitroazobenzene in solvents of different polarities are linearly related to the activation volumes in the same solvents for the thermal cis-trans isomerization of this species, which affords unequivocal evidence for an inversion transition state.",

author = "Norio Nishimura and Tohru Tanaka and Yoshimi Sueishi",

year = "1985",

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doi = "10.1039/C39850000903",

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AU - Nishimura, Norio

AU - Tanaka, Tohru

AU - Sueishi, Yoshimi

PY - 1985/1/1

Y1 - 1985/1/1

N2 - The partial molar volumes of trans-4-dimethylamino-4′-nitroazobenzene in solvents of different polarities are linearly related to the activation volumes in the same solvents for the thermal cis-trans isomerization of this species, which affords unequivocal evidence for an inversion transition state.

AB - The partial molar volumes of trans-4-dimethylamino-4′-nitroazobenzene in solvents of different polarities are linearly related to the activation volumes in the same solvents for the thermal cis-trans isomerization of this species, which affords unequivocal evidence for an inversion transition state.

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JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Evidence of an inversion mechanism for the thermal cis-trans isomerization of push-pull azobenzenes. A volumetric study

Abstract

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