The partial molar volumes of trans-4-dimethylamino-4′-nitroazobenzene in solvents of different polarities are linearly related to the activation volumes in the same solvents for the thermal cis-trans isomerization of this species, which affords unequivocal evidence for an inversion transition state.
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|Publication status||Published - Jan 1 1985|
ASJC Scopus subject areas
- Molecular Medicine