Abstract
In order to obtain essential information on the formation process of the high-Tc phase in the Bi, Pb-Sr-Ca-Cu-O system, subsolidus phase equilibrium in the systems PbO(PbO2)-SrO-CuO and PbO(PbO2)-CaO-SrO has been studied, mainly by XRD analysis. A pseudoternary Pb-Sr-Cu-O solid solution was newly found. This solid solution has a wide solubility range including its typical composition Pb2.03Sr3Cu0.73O7.70. It has a hexagonal structure with lattice parameters a = 10.11 and c = 7.11 in AU. Composition dependences of the lattice parameters and the decomposition (incongruent melting) temperature of (Ca1_xSrx)2PbO4solid solution are also reported.
Original language | English |
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Pages (from-to) | 1397-1402 |
Number of pages | 6 |
Journal | Journal of Materials Research |
Volume | 5 |
Issue number | 7 |
DOIs | |
Publication status | Published - Jul 1990 |
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering