EPR studies at high-pressure. VI. Spin-exchange reaction of nitroxide radical with copper(II) and iron(III) complexes

Yoshimi Sueishi, Arimitsu Hori

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The spin exchange of nitroxide with copper(II) and iron(III) complexes was studied by means of a high-pressure EPR technique. The spin exchange with CuII complexes exhibited the aspect of weak exchange, independent of the kinds of coordinated ligands, while the spin exchange with FeIII complexes was found to vary from weak exchange to a strong one, dependent of the solvent viscosity. Based on the results, the spin exchange with CuII and FeIII complexes is discussed in detail.

Original languageEnglish
Pages (from-to)2431-2432
Number of pages2
JournalBulletin of the Chemical Society of Japan
Volume74
Issue number12
DOIs
Publication statusPublished - Dec 2001

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Paramagnetic resonance
Copper
Iron
Viscosity
Ligands
nitroxyl

ASJC Scopus subject areas

  • Chemistry(all)

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EPR studies at high-pressure. VI. Spin-exchange reaction of nitroxide radical with copper(II) and iron(III) complexes. / Sueishi, Yoshimi; Hori, Arimitsu.

In: Bulletin of the Chemical Society of Japan, Vol. 74, No. 12, 12.2001, p. 2431-2432.

Research output: Contribution to journalArticle

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