Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids

Hiromasa Kiyota, Daisuke Nakashima, Shigefumi Kuwahara, Takayuki Oritani

Research output: Contribution to journal › Article

Abstract

Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.

Original languageEnglish
Pages (from-to)1441-1442
Number of pages2
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume63
Issue number12
Publication statusPublished - 2008
Externally publishedYes

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Lipase
chloroacetic acid

Keywords

  • Bicyclo[2.2.1 ]heptan-2-ol
  • Chloroacetate
  • Enzymatic resolution
  • Lipases
  • Transesterification

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids. / Kiyota, Hiromasa; Nakashima, Daisuke; Kuwahara, Shigefumi; Oritani, Takayuki.

In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 63, No. 12, 2008, p. 1441-1442.

Research output: Contribution to journal › Article

Kiyota, H, Nakashima, D, Kuwahara, S & Oritani, T 2008, 'Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids', Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, vol. 63, no. 12, pp. 1441-1442.
Kiyota H, Nakashima D, Kuwahara S, Oritani T. Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2008;63(12):1441-1442.
Kiyota, Hiromasa ; Nakashima, Daisuke ; Kuwahara, Shigefumi ; Oritani, Takayuki. / Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids. In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2008 ; Vol. 63, No. 12. pp. 1441-1442.
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abstract = "Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.",
keywords = "Bicyclo[2.2.1 ]heptan-2-ol, Chloroacetate, Enzymatic resolution, Lipases, Transesterification",
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AU - Nakashima, Daisuke

AU - Kuwahara, Shigefumi

AU - Oritani, Takayuki

PY - 2008

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KW - Enzymatic resolution

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