Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids

Hiromasa Kiyota; Daisuke Nakashima; Shigefumi Kuwahara; Takayuki Oritani

doi:10.1515/znb-2008-1217

Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids

Hiromasa Kiyota, Daisuke Nakashima, Shigefumi Kuwahara, Takayuki Oritani

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.

Original language	English
Pages (from-to)	1441-1442
Number of pages	2
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	63
Issue number	12
DOIs	https://doi.org/10.1515/znb-2008-1217
Publication status	Published - 2008

Keywords

Bicyclo[2.2.1 ]heptan-2-ol
Chloroacetate
Enzymatic resolution
Lipases
Transesterification

ASJC Scopus subject areas

Chemistry(all)

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10.1515/znb-2008-1217

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Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids. / Kiyota, Hiromasa; Nakashima, Daisuke; Kuwahara, Shigefumi; Oritani, Takayuki.

In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 63, No. 12, 2008, p. 1441-1442.

Research output: Contribution to journal › Article › peer-review

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title = "Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids",

abstract = "Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.",

keywords = "Bicyclo[2.2.1 ]heptan-2-ol, Chloroacetate, Enzymatic resolution, Lipases, Transesterification",

author = "Hiromasa Kiyota and Daisuke Nakashima and Shigefumi Kuwahara and Takayuki Oritani",

note = "Funding Information: We thank Roche Diagnostics K. K. for the gifts of various lipases. This work was partially supported by a Grant-in-aid for Scientific Research from the Japan Society for the Promotion of Science (19580120).",

year = "2008",

doi = "10.1515/znb-2008-1217",

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AU - Kiyota, Hiromasa

AU - Nakashima, Daisuke

AU - Kuwahara, Shigefumi

AU - Oritani, Takayuki

N1 - Funding Information: We thank Roche Diagnostics K. K. for the gifts of various lipases. This work was partially supported by a Grant-in-aid for Scientific Research from the Japan Society for the Promotion of Science (19580120).

PY - 2008

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AB - Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.

KW - Bicyclo[2.2.1 ]heptan-2-ol

KW - Chloroacetate

KW - Enzymatic resolution

KW - Lipases

KW - Transesterification

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