Abstract
The transparent nanocrystallized (heat-treatment: 750 {ring operator}C, 1 h) glasses consisting of ferroelectric Ba2TiSi2O8 nanocrystals (size: 100-200 nm) have been prepared in 40BaO-20TiO2-40SiO2 glass, and the effect of a thermal poling (DC electric voltage: 8.8 kV/cm, temperature: 110-300 {ring operator}C, time: 1 h) on the second harmonic (SH) intensity has been examined. It is found that the formation behavior of nanocrystals at the surface differs from that in the interior of glass, giving a new insight into the well-known concept for nanocrystallization or homogeneous nucleation in glass. The Maker fringe patterns with fine structures are observed, indicating a high orientation of the polarization axes of Ba2TiSi2O8 crystals formed at the surface. The prominent enhancement in the SH intensity is observed due to thermal poling, demonstrating that thermal poling is an effective method in enhancing anisotropic polarization of ferroelectric Ba2TiSi2O8 nanocrystals in crystallized glasses. The present study proposes that the Maker fringe pattern for SH intensity of nanocrystallized glasses is very sensitive to the anisotropic polarization of nanocrystals at the surface, indicating the importance of the Maker fringe technique for the characterization of nanocrystals in materials.
| Original language | English |
|---|---|
| Pages (from-to) | 299-303 |
| Number of pages | 5 |
| Journal | Solid State Communications |
| Volume | 140 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Nov 2006 |
| Externally published | Yes |
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Keywords
- A. Ferroelectrics
- B. Nanofabrication
- D. Optical properties
- E. Nonlinear optics
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
Cite this
Enhancement of second harmonic intensity in thermally poled ferroelectric nanocrystallized glasses in the BaO-TiO2-SiO2 system. / Toyohara, Nozomu; Benino, Yasuhiko; Fujiwara, Takumi; Komatsu, Takayuki.
In: Solid State Communications, Vol. 140, No. 6, 11.2006, p. 299-303.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Enhancement of second harmonic intensity in thermally poled ferroelectric nanocrystallized glasses in the BaO-TiO2-SiO2 system
AU - Toyohara, Nozomu
AU - Benino, Yasuhiko
AU - Fujiwara, Takumi
AU - Komatsu, Takayuki
PY - 2006/11
Y1 - 2006/11
N2 - The transparent nanocrystallized (heat-treatment: 750 {ring operator}C, 1 h) glasses consisting of ferroelectric Ba2TiSi2O8 nanocrystals (size: 100-200 nm) have been prepared in 40BaO-20TiO2-40SiO2 glass, and the effect of a thermal poling (DC electric voltage: 8.8 kV/cm, temperature: 110-300 {ring operator}C, time: 1 h) on the second harmonic (SH) intensity has been examined. It is found that the formation behavior of nanocrystals at the surface differs from that in the interior of glass, giving a new insight into the well-known concept for nanocrystallization or homogeneous nucleation in glass. The Maker fringe patterns with fine structures are observed, indicating a high orientation of the polarization axes of Ba2TiSi2O8 crystals formed at the surface. The prominent enhancement in the SH intensity is observed due to thermal poling, demonstrating that thermal poling is an effective method in enhancing anisotropic polarization of ferroelectric Ba2TiSi2O8 nanocrystals in crystallized glasses. The present study proposes that the Maker fringe pattern for SH intensity of nanocrystallized glasses is very sensitive to the anisotropic polarization of nanocrystals at the surface, indicating the importance of the Maker fringe technique for the characterization of nanocrystals in materials.
AB - The transparent nanocrystallized (heat-treatment: 750 {ring operator}C, 1 h) glasses consisting of ferroelectric Ba2TiSi2O8 nanocrystals (size: 100-200 nm) have been prepared in 40BaO-20TiO2-40SiO2 glass, and the effect of a thermal poling (DC electric voltage: 8.8 kV/cm, temperature: 110-300 {ring operator}C, time: 1 h) on the second harmonic (SH) intensity has been examined. It is found that the formation behavior of nanocrystals at the surface differs from that in the interior of glass, giving a new insight into the well-known concept for nanocrystallization or homogeneous nucleation in glass. The Maker fringe patterns with fine structures are observed, indicating a high orientation of the polarization axes of Ba2TiSi2O8 crystals formed at the surface. The prominent enhancement in the SH intensity is observed due to thermal poling, demonstrating that thermal poling is an effective method in enhancing anisotropic polarization of ferroelectric Ba2TiSi2O8 nanocrystals in crystallized glasses. The present study proposes that the Maker fringe pattern for SH intensity of nanocrystallized glasses is very sensitive to the anisotropic polarization of nanocrystals at the surface, indicating the importance of the Maker fringe technique for the characterization of nanocrystals in materials.
KW - A. Ferroelectrics
KW - B. Nanofabrication
KW - D. Optical properties
KW - E. Nonlinear optics
UR - http://www.scopus.com/inward/record.url?scp=33749263867&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33749263867&partnerID=8YFLogxK
U2 - 10.1016/j.ssc.2006.08.030
DO - 10.1016/j.ssc.2006.08.030
M3 - Article
AN - SCOPUS:33749263867
VL - 140
SP - 299
EP - 303
JO - Solid State Communications
JF - Solid State Communications
SN - 0038-1098
IS - 6
ER -