TY - JOUR
T1 - Enhanced Photosensitized Hydrogen Production by Encapsulation of Ferrocenyl Dyes into Single-Walled Carbon Nanotubes
AU - Murakami, Noritake
AU - Miyake, Hideaki
AU - Tajima, Tomoyuki
AU - Nishikawa, Kakeru
AU - Hirayama, Ryutaro
AU - Takaguchi, Yutaka
N1 - Publisher Copyright:
© 2018 American Chemical Society.
PY - 2018/3/21
Y1 - 2018/3/21
N2 - Dye-encapsulated single-walled carbon nanotubes (SWCNTs) were employed for the construction of a coaxial three-component dye/SWCNT/C60 heterojunction. Despite the larger diameter (∼1.4 nm) of the SWCNTs relative to that set by Flavel's rule (0.95 nm), the photoinduced electron transfer from dye-encapsulated SWCNTs to C60 proceeded smoothly, resulting in the photosensitized evolution of H2 from H2O using a ferrocenyl-based photosensitizer, which was confirmed by the action spectra.
AB - Dye-encapsulated single-walled carbon nanotubes (SWCNTs) were employed for the construction of a coaxial three-component dye/SWCNT/C60 heterojunction. Despite the larger diameter (∼1.4 nm) of the SWCNTs relative to that set by Flavel's rule (0.95 nm), the photoinduced electron transfer from dye-encapsulated SWCNTs to C60 proceeded smoothly, resulting in the photosensitized evolution of H2 from H2O using a ferrocenyl-based photosensitizer, which was confirmed by the action spectra.
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U2 - 10.1021/jacs.7b12845
DO - 10.1021/jacs.7b12845
M3 - Article
C2 - 29502399
AN - SCOPUS:85044243119
VL - 140
SP - 3821
EP - 3824
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 11
ER -