Encapsulation of pyrrole into AlPO4 molecular sieves with chromium ions

Michihiro Miyake, Hirofumi Uehara, Kunihiko Miyake, Mitsuo Sato, Motohide Matsuda

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Encapsulation of pyrrole in one-dimensional channels of AlPO4-5 and AlPO4-11 with chromium ions was attempted by a gas diffusion process and investigated by means of thermoanalytic, spectroscopic and conductivity methods. From the results, it was found that conducting polypyrrole was synthesized in channels of AlPO4-5 with chromium ions which acted as oxidizing agents. Polypyrrole, however, could not be occluded in channels of AlPO4-11 with chromium ions.

Original languageEnglish
Pages (from-to)227-232
Number of pages6
JournalJournal of Porous Materials
Volume3
Issue number4
DOIs
Publication statusPublished - Jan 1 1996

Keywords

  • Aluminophosphate molecular sieve AlPO-5
  • Cluster
  • Encapsulation
  • Host-guest reaction
  • Polypyrrole

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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