We report a highly diastereo- and enantioselective synthesis of anti homoallylic alcohols from terminal alkynes via (E)-1-alkenylboronates based upon two catalytic reactions: a cationic iridium complex-catalyzed olefin transposition of (E)-1-alkenylboronates and a chiral phosphoric acid-catalyzed allylation reaction of aldehydes.
|Number of pages||4|
|Journal||Journal of the American Chemical Society|
|Publication status||Published - Aug 7 2013|
ASJC Scopus subject areas
- Colloid and Surface Chemistry