Enantioselective [2 + 2 + 2] cycloaddition reaction of isocyanates and allenes catalyzed by nickel

Tomoya Miura, Masao Morimoto, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

56 Citations (Scopus)

Abstract

The enantioselective intermolecular [2 + 2 + 2] cycloaddition reaction of two molecules of isocyanate and one molecule of allene is catalyzed by a nickel(0)/(S,S)-i-Pr-FOXAP complex, providing an efficient access to enantiomerically enriched dihydropyrimidine-2,4-diones.

Original languageEnglish
Pages (from-to)15836-15838
Number of pages3
JournalJournal of the American Chemical Society
Volume132
Issue number45
DOIs
Publication statusPublished - Nov 17 2010
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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