Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system

Approach to totally closed system

Manabu Kuroboshi, Kentaro Goto, Hideo Tanaka

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO3 solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.

Original languageEnglish
Article numberF20808SS
Pages (from-to)903-908
Number of pages6
JournalSynthesis
Issue number6
DOIs
Publication statusPublished - Mar 2009

Fingerprint

Electrooxidation
Silica Gel
Silica gel
Alcohols
Water
Silanes
Carbonyl compounds
Recycling

Keywords

  • Alcohols
  • Electron transfer
  • Oxidations
  • Solid-phase synthesis

ASJC Scopus subject areas

  • Organic Chemistry
  • Catalysis

Cite this

Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system : Approach to totally closed system. / Kuroboshi, Manabu; Goto, Kentaro; Tanaka, Hideo.

In: Synthesis, No. 6, F20808SS, 03.2009, p. 903-908.

Research output: Contribution to journalArticle

@article{f2fd74a93592412ab75f4fe3867bc902,
title = "Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system: Approach to totally closed system",
abstract = "Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO3 solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.",
keywords = "Alcohols, Electron transfer, Oxidations, Solid-phase synthesis",
author = "Manabu Kuroboshi and Kentaro Goto and Hideo Tanaka",
year = "2009",
month = "3",
doi = "10.1055/s-0028-1087987",
language = "English",
pages = "903--908",
journal = "Synthesis",
issn = "0039-7881",
publisher = "Georg Thieme Verlag",
number = "6",

}

TY - JOUR

T1 - Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system

T2 - Approach to totally closed system

AU - Kuroboshi, Manabu

AU - Goto, Kentaro

AU - Tanaka, Hideo

PY - 2009/3

Y1 - 2009/3

N2 - Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO3 solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.

AB - Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO3 solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.

KW - Alcohols

KW - Electron transfer

KW - Oxidations

KW - Solid-phase synthesis

UR - http://www.scopus.com/inward/record.url?scp=67649421207&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67649421207&partnerID=8YFLogxK

U2 - 10.1055/s-0028-1087987

DO - 10.1055/s-0028-1087987

M3 - Article

SP - 903

EP - 908

JO - Synthesis

JF - Synthesis

SN - 0039-7881

IS - 6

M1 - F20808SS

ER -