Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system: Approach to totally closed system

Manabu Kuroboshi, Kentaro Goto, Hideo Tanaka

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO3 solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.

Original languageEnglish
Article numberF20808SS
Pages (from-to)903-908
Number of pages6
JournalSynthesis
Issue number6
DOIs
Publication statusPublished - Mar 1 2009

Keywords

  • Alcohols
  • Electron transfer
  • Oxidations
  • Solid-phase synthesis

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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