Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system

Jun Kubota, Toru Ido, Manabu Kuroboshi, Hideo Tanaka, Tetsuya Uchida, Kaoru Shimamura

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The electrooxidation of alcohols in an aqueous disperse system with N-oxyl-immobilized poly(p-phenylene benzobisthiazole) network polymer particles (PBZTNT-N-Oxyl) as a disperse phase was performed successfully in a simple beaker-type undivided cell under a constant current condition to afford the corresponding ketones, aldehydes, and/or carboxylic acid in moderate to good yields. Recycle use of both the PBZTNT-N-Oxyl particles and the aqueous media could be achieved successfully by immobilization of additional N-oxyl moiety on the polymer particles in an appropriate interval. Notably, the shape and the particle size of PBZTNT-N-Oxyl were not appreciably changed even after 60 times recycle use.

Original languageEnglish
Pages (from-to)4769-4773
Number of pages5
JournalTetrahedron
Volume62
Issue number20
DOIs
Publication statusPublished - May 15 2006

Fingerprint

Electrooxidation
Polymers
Alcohols
Water
Carboxylic Acids
Ketones
Particle Size
Aldehydes
Immobilization
Particle size
poly-para-phenylene

Keywords

  • Alcohols
  • Aqueous solution
  • Disperse system
  • Electrooxidation
  • Polymer-supported N-oxyl

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system. / Kubota, Jun; Ido, Toru; Kuroboshi, Manabu; Tanaka, Hideo; Uchida, Tetsuya; Shimamura, Kaoru.

In: Tetrahedron, Vol. 62, No. 20, 15.05.2006, p. 4769-4773.

Research output: Contribution to journalArticle

Kubota, Jun ; Ido, Toru ; Kuroboshi, Manabu ; Tanaka, Hideo ; Uchida, Tetsuya ; Shimamura, Kaoru. / Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system. In: Tetrahedron. 2006 ; Vol. 62, No. 20. pp. 4769-4773.
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