Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system

Jun Kubota; Toru Ido; Manabu Kuroboshi; Hideo Tanaka; Tetsuya Uchida; Kaoru Shimamura

doi:10.1016/j.tet.2006.03.020

Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system

Jun Kubota, Toru Ido, Manabu Kuroboshi, Hideo Tanaka, Tetsuya Uchida, Kaoru Shimamura

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The electrooxidation of alcohols in an aqueous disperse system with N-oxyl-immobilized poly(p-phenylene benzobisthiazole) network polymer particles (PBZT_NT-N-Oxyl) as a disperse phase was performed successfully in a simple beaker-type undivided cell under a constant current condition to afford the corresponding ketones, aldehydes, and/or carboxylic acid in moderate to good yields. Recycle use of both the PBZT_NT-N-Oxyl particles and the aqueous media could be achieved successfully by immobilization of additional N-oxyl moiety on the polymer particles in an appropriate interval. Notably, the shape and the particle size of PBZT_NT-N-Oxyl were not appreciably changed even after 60 times recycle use.

Original language	English
Pages (from-to)	4769-4773
Number of pages	5
Journal	Tetrahedron
Volume	62
Issue number	20
DOIs	https://doi.org/10.1016/j.tet.2006.03.020
Publication status	Published - May 15 2006

Keywords

Alcohols
Aqueous solution
Disperse system
Electrooxidation
Polymer-supported N-oxyl

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2006.03.020

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title = "Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system",

abstract = "The electrooxidation of alcohols in an aqueous disperse system with N-oxyl-immobilized poly(p-phenylene benzobisthiazole) network polymer particles (PBZTNT-N-Oxyl) as a disperse phase was performed successfully in a simple beaker-type undivided cell under a constant current condition to afford the corresponding ketones, aldehydes, and/or carboxylic acid in moderate to good yields. Recycle use of both the PBZTNT-N-Oxyl particles and the aqueous media could be achieved successfully by immobilization of additional N-oxyl moiety on the polymer particles in an appropriate interval. Notably, the shape and the particle size of PBZTNT-N-Oxyl were not appreciably changed even after 60 times recycle use.",

keywords = "Alcohols, Aqueous solution, Disperse system, Electrooxidation, Polymer-supported N-oxyl",

author = "Jun Kubota and Toru Ido and Manabu Kuroboshi and Hideo Tanaka and Tetsuya Uchida and Kaoru Shimamura",

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T1 - Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system

AU - Kubota, Jun

AU - Ido, Toru

AU - Kuroboshi, Manabu

AU - Tanaka, Hideo

AU - Uchida, Tetsuya

AU - Shimamura, Kaoru

PY - 2006/5/15

Y1 - 2006/5/15

N2 - The electrooxidation of alcohols in an aqueous disperse system with N-oxyl-immobilized poly(p-phenylene benzobisthiazole) network polymer particles (PBZTNT-N-Oxyl) as a disperse phase was performed successfully in a simple beaker-type undivided cell under a constant current condition to afford the corresponding ketones, aldehydes, and/or carboxylic acid in moderate to good yields. Recycle use of both the PBZTNT-N-Oxyl particles and the aqueous media could be achieved successfully by immobilization of additional N-oxyl moiety on the polymer particles in an appropriate interval. Notably, the shape and the particle size of PBZTNT-N-Oxyl were not appreciably changed even after 60 times recycle use.

AB - The electrooxidation of alcohols in an aqueous disperse system with N-oxyl-immobilized poly(p-phenylene benzobisthiazole) network polymer particles (PBZTNT-N-Oxyl) as a disperse phase was performed successfully in a simple beaker-type undivided cell under a constant current condition to afford the corresponding ketones, aldehydes, and/or carboxylic acid in moderate to good yields. Recycle use of both the PBZTNT-N-Oxyl particles and the aqueous media could be achieved successfully by immobilization of additional N-oxyl moiety on the polymer particles in an appropriate interval. Notably, the shape and the particle size of PBZTNT-N-Oxyl were not appreciably changed even after 60 times recycle use.

KW - Alcohols

KW - Aqueous solution

KW - Disperse system

KW - Electrooxidation

KW - Polymer-supported N-oxyl

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DO - 10.1016/j.tet.2006.03.020

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JF - Tetrahedron

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ER -

Electrooxidation of alcohols in an N-oxyl-immobilized rigid network polymer particles/water disperse system

Abstract

Keywords

ASJC Scopus subject areas

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