The electronic polarizability and optical basicity of La2O3 and related glasses have been determined from ultraviolet absorption spectra and calculations based on the Lorentz-Lorenz equation. The optical basicity for La2O3 oxide is found to be 1.07, being much larger compared with typical glass-forming oxides such as B2O3 (0.42) and SiO2 (0.48) but being similar to heavy element oxides such as TeO2 (0.93). The Yamashita and Kurosawa's interaction parameter of La2O3 is 0.03 Å-3, indicating that La2O3 is classified as a normal ionic (basic) oxide, i.e., an ionic bonding character in the La3+-O bond is proposed. Close correlations are confirmed among optical basicity, interaction parameter, and oxygen 1s binding energy in x-ray photoelectron (XPS) spectra for La2O3-P2O5 and other La2O3-containing glasses. It is found from XPS and Raman spectra that La3+ ions in La2O3-P2O5 glasses act as network modifiers, supporting an ionic bonding character in the La3+-O bond. The parameters related to electronic polarizability in La2O3 determined in the present study would be useful for the design of rare-earth containing optical functional glasses.
ASJC Scopus subject areas
- Physics and Astronomy(all)