Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes

T. Hasegawa; T. Akutagawa; T. Nakamura; Y. Sasou; R. Kondo; S. Kagoshima; T. Mochida; G. Saito; Y. Iwasa

doi:10.1016/S0379-6779(98)00443-3

Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes

T. Hasegawa, T. Akutagawa, T. Nakamura, Y. Sasou, R. Kondo, S. Kagoshima, T. Mochida, G. Saito, Y. Iwasa

Research output: Contribution to journal › Conference article

4 Citations (Scopus)

Abstract

The BEDT-TTF based mixed-stack charge-transfer (CT) complexes have been investigated for a series of isostructural compounds. The ionic complex of (BEDO-TTF)(Cl₂TCNQ) is a magnetic insulator with showing Curie-Weiss behavior in magnetic susceptibility, in sharp contrast to the conventional mixed-stack CT complexes. The (BEDT-TTF)(ClMeTCNQ) compound undergoes neutral-ionic (NI) phase transition at high pressure.

Original language	English
Pages (from-to)	1804-1805
Number of pages	2
Journal	Synthetic Metals
Volume	103
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00443-3
Publication status	Published - Jun 24 1999
Externally published	Yes
Event	Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Duration: Jul 12 1998 → Jul 18 1998

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ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Cite this

Hasegawa, T., Akutagawa, T., Nakamura, T., Sasou, Y., Kondo, R., Kagoshima, S., Mochida, T., Saito, G., & Iwasa, Y. (1999). Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes. Synthetic Metals, 103(1-3), 1804-1805. https://doi.org/10.1016/S0379-6779(98)00443-3

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abstract = "The BEDT-TTF based mixed-stack charge-transfer (CT) complexes have been investigated for a series of isostructural compounds. The ionic complex of (BEDO-TTF)(Cl2TCNQ) is a magnetic insulator with showing Curie-Weiss behavior in magnetic susceptibility, in sharp contrast to the conventional mixed-stack CT complexes. The (BEDT-TTF)(ClMeTCNQ) compound undergoes neutral-ionic (NI) phase transition at high pressure.",

author = "T. Hasegawa and T. Akutagawa and T. Nakamura and Y. Sasou and R. Kondo and S. Kagoshima and T. Mochida and G. Saito and Y. Iwasa",

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T1 - Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes

AU - Hasegawa, T.

AU - Akutagawa, T.

AU - Nakamura, T.

AU - Sasou, Y.

AU - Kondo, R.

AU - Kagoshima, S.

AU - Mochida, T.

AU - Saito, G.

AU - Iwasa, Y.

PY - 1999/6/24

Y1 - 1999/6/24

N2 - The BEDT-TTF based mixed-stack charge-transfer (CT) complexes have been investigated for a series of isostructural compounds. The ionic complex of (BEDO-TTF)(Cl2TCNQ) is a magnetic insulator with showing Curie-Weiss behavior in magnetic susceptibility, in sharp contrast to the conventional mixed-stack CT complexes. The (BEDT-TTF)(ClMeTCNQ) compound undergoes neutral-ionic (NI) phase transition at high pressure.

AB - The BEDT-TTF based mixed-stack charge-transfer (CT) complexes have been investigated for a series of isostructural compounds. The ionic complex of (BEDO-TTF)(Cl2TCNQ) is a magnetic insulator with showing Curie-Weiss behavior in magnetic susceptibility, in sharp contrast to the conventional mixed-stack CT complexes. The (BEDT-TTF)(ClMeTCNQ) compound undergoes neutral-ionic (NI) phase transition at high pressure.

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VL - 103

SP - 1804

EP - 1805

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

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10.1016/S0379-6779(98)00443-3