Electrochemical studies on molten sodium hydroxide

Hidetaka Hayashi, Shiro Yoshizawa, Yasuhiko Ito

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Abstract

The EpO2- diagram is very instructive for the selection of corrosion-resistant materials. In the molten hydroxide system, the equilibrium constant K1 of the reaction 2 OH- = H2O + O2- is one of the basic data for the EpO2- diagram. In order to obtain the constant K1, we determined the chemical potential of Na2O(μ°(Na2O)) dissolved in molten sodium hydroxide at 623 K (350°C) to be -4.71 × 105 J mol-1, by the use of the following cell: Na/beta-alumina/NaOH(Na2O)/ZrO2Y2O3/O2(Pt) K1 calculated from the above experimental data is then 1.0 × 10-10 atm.

Original languageEnglish
Pages (from-to)229-235
Number of pages7
JournalJournal of Electroanalytical Chemistry
Volume124
Issue number1-2
Publication statusPublished - Jul 10 1981
Externally publishedYes

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ASJC Scopus subject areas

  • Electrochemistry
  • Analytical Chemistry
  • Chemical Engineering(all)

Cite this

Hayashi, H., Yoshizawa, S., & Ito, Y. (1981). Electrochemical studies on molten sodium hydroxide. Journal of Electroanalytical Chemistry, 124(1-2), 229-235.