Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions

Koichi Mitsudo; Takashi Kaide; Eriko Nakamoto; Kenta Yoshida; Hideo Tanaka

doi:10.1021/ja069043r

Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions

Koichi Mitsudo, Takashi Kaide, Eriko Nakamoto, Kenta Yoshida, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

We have developed an electrooxidative method for generating cationic palladium complexes [Pd(CH₃CN)₄][X]₂ (X = BF₄, PF₆, and ClO₄) from Pd(OAc)₂ and several electrolytes bearing X groups in CH₃CN. The system could be integrated into an electrochemical Wacker-type reaction. In the presence of a catalytic amount of TEMPO, the reaction proceeded smoothly to give the corresponding methyl ketones.

Original language	English
Pages (from-to)	2246-2247
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	8
DOIs	https://doi.org/10.1021/ja069043r
Publication status	Published - Feb 28 2007

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions. / Mitsudo, Koichi; Kaide, Takashi; Nakamoto, Eriko; Yoshida, Kenta; Tanaka, Hideo.

In: Journal of the American Chemical Society, Vol. 129, No. 8, 28.02.2007, p. 2246-2247.

Research output: Contribution to journal › Article › peer-review

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abstract = "We have developed an electrooxidative method for generating cationic palladium complexes [Pd(CH3CN)4][X]2 (X = BF4, PF6, and ClO4) from Pd(OAc)2 and several electrolytes bearing X groups in CH3CN. The system could be integrated into an electrochemical Wacker-type reaction. In the presence of a catalytic amount of TEMPO, the reaction proceeded smoothly to give the corresponding methyl ketones.",

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AU - Mitsudo, Koichi

AU - Kaide, Takashi

AU - Nakamoto, Eriko

AU - Yoshida, Kenta

AU - Tanaka, Hideo

PY - 2007/2/28

Y1 - 2007/2/28

N2 - We have developed an electrooxidative method for generating cationic palladium complexes [Pd(CH3CN)4][X]2 (X = BF4, PF6, and ClO4) from Pd(OAc)2 and several electrolytes bearing X groups in CH3CN. The system could be integrated into an electrochemical Wacker-type reaction. In the presence of a catalytic amount of TEMPO, the reaction proceeded smoothly to give the corresponding methyl ketones.

AB - We have developed an electrooxidative method for generating cationic palladium complexes [Pd(CH3CN)4][X]2 (X = BF4, PF6, and ClO4) from Pd(OAc)2 and several electrolytes bearing X groups in CH3CN. The system could be integrated into an electrochemical Wacker-type reaction. In the presence of a catalytic amount of TEMPO, the reaction proceeded smoothly to give the corresponding methyl ketones.

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Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions

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