Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions

Koichi Mitsudo, Takashi Kaide, Eriko Nakamoto, Kenta Yoshida, Hideo Tanaka

Research output: Contribution to journal › Article

54 Citations (Scopus)

Abstract

We have developed an electrooxidative method for generating cationic palladium complexes [Pd(CH3CN)4][X]2 (X = BF4, PF6, and ClO4) from Pd(OAc)2 and several electrolytes bearing X groups in CH3CN. The system could be integrated into an electrochemical Wacker-type reaction. In the presence of a catalytic amount of TEMPO, the reaction proceeded smoothly to give the corresponding methyl ketones.

Original languageEnglish
Pages (from-to)2246-2247
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number8
DOIs
Publication statusPublished - Feb 28 2007

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Bearings (structural)
Palladium
Ketones
Electrolytes
Catalysts
TEMPO
perchlorate
palladium(II) acetate

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions. / Mitsudo, Koichi; Kaide, Takashi; Nakamoto, Eriko; Yoshida, Kenta; Tanaka, Hideo.

In: Journal of the American Chemical Society, Vol. 129, No. 8, 28.02.2007, p. 2246-2247.

Research output: Contribution to journal › Article

Mitsudo, K, Kaide, T, Nakamoto, E, Yoshida, K & Tanaka, H 2007, 'Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions', Journal of the American Chemical Society, vol. 129, no. 8, pp. 2246-2247. https://doi.org/10.1021/ja069043r
Mitsudo K, Kaide T, Nakamoto E, Yoshida K, Tanaka H. Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions. Journal of the American Chemical Society. 2007 Feb 28;129(8):2246-2247. https://doi.org/10.1021/ja069043r
Mitsudo, Koichi ; Kaide, Takashi ; Nakamoto, Eriko ; Yoshida, Kenta ; Tanaka, Hideo. / Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions. In: Journal of the American Chemical Society. 2007 ; Vol. 129, No. 8. pp. 2246-2247.
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