Abstract
We have developed an electrooxidative method for generating cationic palladium complexes [Pd(CH3CN)4][X]2 (X = BF4, PF6, and ClO4) from Pd(OAc)2 and several electrolytes bearing X groups in CH3CN. The system could be integrated into an electrochemical Wacker-type reaction. In the presence of a catalytic amount of TEMPO, the reaction proceeded smoothly to give the corresponding methyl ketones.
Original language | English |
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Pages (from-to) | 2246-2247 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 129 |
Issue number | 8 |
DOIs | |
Publication status | Published - Feb 28 2007 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry