Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex

Hideo Tanaka; Manabu Kuroboshi; Hironori Takeda; Hisaaki Kanda; Sigeni Torii

doi:10.1016/S0022-0728(01)00387-4

Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex

Hideo Tanaka, Manabu Kuroboshi, Hironori Takeda, Hisaaki Kanda, Sigeni Torii

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Enantioselective electro-epoxidation of olefins by using an optically active Mn-salen complex, (S,S)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1, 2-cyclohexanediaminomanganese(III) chloride (3), as a mediator in a CH₂Cl₂ aqueous NaCl two-phase system was performed successfully in a simple undivided cell under constant current conditions. Optimization of the electrolysis conditions and estimation of the reaction mechanism are discussed.

Original language	English
Pages (from-to)	75-81
Number of pages	7
Journal	Journal of Electroanalytical Chemistry
Volume	507
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-0728(01)00387-4
Publication status	Published - Jul 13 2001

Keywords

Alkenes
Asymmetric induction
Electrochemical reaction
Epoxidation
Manganese compounds

ASJC Scopus subject areas

Analytical Chemistry
Chemical Engineering(all)
Electrochemistry

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10.1016/S0022-0728(01)00387-4

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title = "Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex",

abstract = "Enantioselective electro-epoxidation of olefins by using an optically active Mn-salen complex, (S,S)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1, 2-cyclohexanediaminomanganese(III) chloride (3), as a mediator in a CH2Cl2 aqueous NaCl two-phase system was performed successfully in a simple undivided cell under constant current conditions. Optimization of the electrolysis conditions and estimation of the reaction mechanism are discussed.",

keywords = "Alkenes, Asymmetric induction, Electrochemical reaction, Epoxidation, Manganese compounds",

author = "Hideo Tanaka and Manabu Kuroboshi and Hironori Takeda and Hisaaki Kanda and Sigeni Torii",

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doi = "10.1016/S0022-0728(01)00387-4",

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T1 - Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex

AU - Tanaka, Hideo

AU - Kuroboshi, Manabu

AU - Takeda, Hironori

AU - Kanda, Hisaaki

AU - Torii, Sigeni

PY - 2001/7/13

Y1 - 2001/7/13

N2 - Enantioselective electro-epoxidation of olefins by using an optically active Mn-salen complex, (S,S)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1, 2-cyclohexanediaminomanganese(III) chloride (3), as a mediator in a CH2Cl2 aqueous NaCl two-phase system was performed successfully in a simple undivided cell under constant current conditions. Optimization of the electrolysis conditions and estimation of the reaction mechanism are discussed.

AB - Enantioselective electro-epoxidation of olefins by using an optically active Mn-salen complex, (S,S)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1, 2-cyclohexanediaminomanganese(III) chloride (3), as a mediator in a CH2Cl2 aqueous NaCl two-phase system was performed successfully in a simple undivided cell under constant current conditions. Optimization of the electrolysis conditions and estimation of the reaction mechanism are discussed.

KW - Alkenes

KW - Asymmetric induction

KW - Electrochemical reaction

KW - Epoxidation

KW - Manganese compounds

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JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1-2

ER -

Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex

Abstract

Keywords

ASJC Scopus subject areas

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