Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex

H. Tanaka, Manabu Kuroboshi, H. Takeda, H. Kanda, S. Torii

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Enantioselective electro-epoxidation of olefins by using an optically active Mn-salen complex, (S,S)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1, 2-cyclohexanediaminomanganese(III) chloride (3), as a mediator in a CH2Cl2 aqueous NaCl two-phase system was performed successfully in a simple undivided cell under constant current conditions. Optimization of the electrolysis conditions and estimation of the reaction mechanism are discussed.

Original languageEnglish
Pages (from-to)75-81
Number of pages7
JournalJournal of Electroanalytical Chemistry
Volume507
Issue number1-2
DOIs
Publication statusPublished - Jul 13 2001

Fingerprint

Epoxidation
Alkenes
Electrolysis
Olefins
Chlorides
Mn-salen

Keywords

  • Alkenes
  • Asymmetric induction
  • Electrochemical reaction
  • Epoxidation
  • Manganese compounds

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Analytical Chemistry
  • Electrochemistry

Cite this

Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex. / Tanaka, H.; Kuroboshi, Manabu; Takeda, H.; Kanda, H.; Torii, S.

In: Journal of Electroanalytical Chemistry, Vol. 507, No. 1-2, 13.07.2001, p. 75-81.

Research output: Contribution to journalArticle

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AU - Tanaka, H.

AU - Kuroboshi, Manabu

AU - Takeda, H.

AU - Kanda, H.

AU - Torii, S.

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