Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile

Koichi Mitsudo; Takahiro Okada; Shuichi Shimohara; Hiroki Mandai; Seiji Suga

doi:10.5796/electrochemistry.81.362

Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile

Koichi Mitsudo, Takahiro Okada, Shuichi Shimohara, Hiroki Mandai, Seiji Suga

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

An electro-reductive halogen-deuterium exchange reaction in CD ₃CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions.

Original language	English
Pages (from-to)	362-364
Number of pages	3
Journal	Electrochemistry
Volume	81
Issue number	5
DOIs	https://doi.org/10.5796/electrochemistry.81.362
Publication status	Published - May 2013

Keywords

Deuteriation
Electro-reduction
Halogen-deuterium exchange
Methylation

ASJC Scopus subject areas

Electrochemistry

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10.5796/electrochemistry.81.362

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abstract = "An electro-reductive halogen-deuterium exchange reaction in CD 3CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions.",

keywords = "Deuteriation, Electro-reduction, Halogen-deuterium exchange, Methylation",

author = "Koichi Mitsudo and Takahiro Okada and Shuichi Shimohara and Hiroki Mandai and Seiji Suga",

year = "2013",

month = may,

doi = "10.5796/electrochemistry.81.362",

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T1 - Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile

AU - Mitsudo, Koichi

AU - Okada, Takahiro

AU - Shimohara, Shuichi

AU - Mandai, Hiroki

AU - Suga, Seiji

PY - 2013/5

Y1 - 2013/5

N2 - An electro-reductive halogen-deuterium exchange reaction in CD 3CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions.

AB - An electro-reductive halogen-deuterium exchange reaction in CD 3CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions.

KW - Deuteriation

KW - Electro-reduction

KW - Halogen-deuterium exchange

KW - Methylation

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M3 - Article

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Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile

Abstract

Keywords

ASJC Scopus subject areas

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