Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile

Koichi Mitsudo, Takahiro Okada, Shuichi Shimohara, Hiroki Mandai, Seiji Suga

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

An electro-reductive halogen-deuterium exchange reaction in CD 3CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions.

Original languageEnglish
Pages (from-to)362-364
Number of pages3
JournalElectrochemistry
Volume81
Issue number5
DOIs
Publication statusPublished - May 2013

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Halogens
Methylation
Deuterium
Acetonitrile
Ion exchange
9-fluorenone
acetonitrile

Keywords

  • Deuteriation
  • Electro-reduction
  • Halogen-deuterium exchange
  • Methylation

ASJC Scopus subject areas

  • Electrochemistry

Cite this

Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile. / Mitsudo, Koichi; Okada, Takahiro; Shimohara, Shuichi; Mandai, Hiroki; Suga, Seiji.

In: Electrochemistry, Vol. 81, No. 5, 05.2013, p. 362-364.

Research output: Contribution to journal › Article

Mitsudo, K, Okada, T, Shimohara, S, Mandai, H & Suga, S 2013, 'Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile', Electrochemistry, vol. 81, no. 5, pp. 362-364. https://doi.org/10.5796/electrochemistry.81.362
Mitsudo K, Okada T, Shimohara S, Mandai H, Suga S. Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile. Electrochemistry. 2013 May;81(5):362-364. https://doi.org/10.5796/electrochemistry.81.362
Mitsudo, Koichi ; Okada, Takahiro ; Shimohara, Shuichi ; Mandai, Hiroki ; Suga, Seiji. / Electro-reductive halogen-deuterium exchange and methylation of aryl halides in acetonitrile. In: Electrochemistry. 2013 ; Vol. 81, No. 5. pp. 362-364.
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