Electro-initiated coupling reactions of N-acyliminium ion pools with arylthiomethylsilanes and aryloxymethylsilanes

Seiji Suga, Ikuo Shimizu, Yosuke Ashikari, Yusuke Mizuno, Tomokazu Maruyama, Jun ichi Yoshida

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Abstract

Electro-initiated coupling reactions of N-acyliminium ion with arylthiomethylsilanes and aryloxymethylsilanes were developed. Pulse electrolyses with intervals were found to be quite effective for the initiation. A chain mechanism involving cation, radical cation, and radical intermediates has been proposed.

Original languageEnglish
Pages (from-to)1008-1009
Number of pages2
JournalChemistry Letters
Volume37
Issue number9
DOIs
Publication statusPublished - Sep 5 2008
Externally publishedYes

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Electro-initiated coupling reactions of N-acyliminium ion pools with arylthiomethylsilanes and aryloxymethylsilanes. / Suga, Seiji; Shimizu, Ikuo; Ashikari, Yosuke; Mizuno, Yusuke; Maruyama, Tomokazu; Yoshida, Jun ichi.

In: Chemistry Letters, Vol. 37, No. 9, 05.09.2008, p. 1008-1009.

Research output: Contribution to journalArticle

Suga, Seiji ; Shimizu, Ikuo ; Ashikari, Yosuke ; Mizuno, Yusuke ; Maruyama, Tomokazu ; Yoshida, Jun ichi. / Electro-initiated coupling reactions of N-acyliminium ion pools with arylthiomethylsilanes and aryloxymethylsilanes. In: Chemistry Letters. 2008 ; Vol. 37, No. 9. pp. 1008-1009.
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