Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions

Hossein Loghmani-Khouzani, Panteha Tamjidi, Iraj Mohammadpoor-Baltork, Marzieh Yaeghoobi, Noorsaadah Abd Rahman, Ahmad Reza Khosropour, Majid Moghadam, Shahram Tangestaninejad, Valiolah Mirkhani, Mohammad Hossein Habibi, Ayana Kashima, Takayoshi Suzuki

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system.

Original languageEnglish
Pages (from-to)138-150
Number of pages13
JournalJournal of Heterocyclic Chemistry
Volume51
Issue number1
DOIs
Publication statusPublished - Jan 2014

Fingerprint

Thiazepines
Benzodiazepines
Thiazines
Nitrates
Crystal structure
Derivatives
Catalysts
1,5-benzothiazepine

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions. / Loghmani-Khouzani, Hossein; Tamjidi, Panteha; Mohammadpoor-Baltork, Iraj; Yaeghoobi, Marzieh; Rahman, Noorsaadah Abd; Khosropour, Ahmad Reza; Moghadam, Majid; Tangestaninejad, Shahram; Mirkhani, Valiolah; Habibi, Mohammad Hossein; Kashima, Ayana; Suzuki, Takayoshi.

In: Journal of Heterocyclic Chemistry, Vol. 51, No. 1, 01.2014, p. 138-150.

Research output: Contribution to journalArticle

Loghmani-Khouzani, H, Tamjidi, P, Mohammadpoor-Baltork, I, Yaeghoobi, M, Rahman, NA, Khosropour, AR, Moghadam, M, Tangestaninejad, S, Mirkhani, V, Habibi, MH, Kashima, A & Suzuki, T 2014, 'Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions', Journal of Heterocyclic Chemistry, vol. 51, no. 1, pp. 138-150. https://doi.org/10.1002/jhet.1827
Loghmani-Khouzani, Hossein ; Tamjidi, Panteha ; Mohammadpoor-Baltork, Iraj ; Yaeghoobi, Marzieh ; Rahman, Noorsaadah Abd ; Khosropour, Ahmad Reza ; Moghadam, Majid ; Tangestaninejad, Shahram ; Mirkhani, Valiolah ; Habibi, Mohammad Hossein ; Kashima, Ayana ; Suzuki, Takayoshi. / Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions. In: Journal of Heterocyclic Chemistry. 2014 ; Vol. 51, No. 1. pp. 138-150.
@article{4fdbf24c86a149fe9edb5b8e74e47206,
title = "Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions",
abstract = "This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system.",
author = "Hossein Loghmani-Khouzani and Panteha Tamjidi and Iraj Mohammadpoor-Baltork and Marzieh Yaeghoobi and Rahman, {Noorsaadah Abd} and Khosropour, {Ahmad Reza} and Majid Moghadam and Shahram Tangestaninejad and Valiolah Mirkhani and Habibi, {Mohammad Hossein} and Ayana Kashima and Takayoshi Suzuki",
year = "2014",
month = "1",
doi = "10.1002/jhet.1827",
language = "English",
volume = "51",
pages = "138--150",
journal = "Journal of Heterocyclic Chemistry",
issn = "0022-152X",
publisher = "Heterocorporation",
number = "1",

}

TY - JOUR

T1 - Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions

AU - Loghmani-Khouzani, Hossein

AU - Tamjidi, Panteha

AU - Mohammadpoor-Baltork, Iraj

AU - Yaeghoobi, Marzieh

AU - Rahman, Noorsaadah Abd

AU - Khosropour, Ahmad Reza

AU - Moghadam, Majid

AU - Tangestaninejad, Shahram

AU - Mirkhani, Valiolah

AU - Habibi, Mohammad Hossein

AU - Kashima, Ayana

AU - Suzuki, Takayoshi

PY - 2014/1

Y1 - 2014/1

N2 - This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system.

AB - This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system.

UR - http://www.scopus.com/inward/record.url?scp=84894905413&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84894905413&partnerID=8YFLogxK

U2 - 10.1002/jhet.1827

DO - 10.1002/jhet.1827

M3 - Article

AN - SCOPUS:84894905413

VL - 51

SP - 138

EP - 150

JO - Journal of Heterocyclic Chemistry

JF - Journal of Heterocyclic Chemistry

SN - 0022-152X

IS - 1

ER -