Abstract
This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system.
| Original language | English |
|---|---|
| Pages (from-to) | 138-150 |
| Number of pages | 13 |
| Journal | Journal of Heterocyclic Chemistry |
| Volume | 51 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 2014 |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions. / Loghmani-Khouzani, Hossein; Tamjidi, Panteha; Mohammadpoor-Baltork, Iraj; Yaeghoobi, Marzieh; Rahman, Noorsaadah Abd; Khosropour, Ahmad Reza; Moghadam, Majid; Tangestaninejad, Shahram; Mirkhani, Valiolah; Habibi, Mohammad Hossein; Kashima, Ayana; Suzuki, Takayoshi.
In: Journal of Heterocyclic Chemistry, Vol. 51, No. 1, 01.2014, p. 138-150.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions
AU - Loghmani-Khouzani, Hossein
AU - Tamjidi, Panteha
AU - Mohammadpoor-Baltork, Iraj
AU - Yaeghoobi, Marzieh
AU - Rahman, Noorsaadah Abd
AU - Khosropour, Ahmad Reza
AU - Moghadam, Majid
AU - Tangestaninejad, Shahram
AU - Mirkhani, Valiolah
AU - Habibi, Mohammad Hossein
AU - Kashima, Ayana
AU - Suzuki, Takayoshi
PY - 2014/1
Y1 - 2014/1
N2 - This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system.
AB - This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system.
UR - http://www.scopus.com/inward/record.url?scp=84894905413&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84894905413&partnerID=8YFLogxK
U2 - 10.1002/jhet.1827
DO - 10.1002/jhet.1827
M3 - Article
AN - SCOPUS:84894905413
VL - 51
SP - 138
EP - 150
JO - Journal of Heterocyclic Chemistry
JF - Journal of Heterocyclic Chemistry
SN - 0022-152X
IS - 1
ER -