Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions

Hossein Loghmani-Khouzani; Panteha Tamjidi; Iraj Mohammadpoor-Baltork; Marzieh Yaeghoobi; Noorsaadah Abd Rahman; Ahmad Reza Khosropour; Majid Moghadam; Shahram Tangestaninejad; Valiolah Mirkhani; Mohammad Hossein Habibi; Ayana Kashima; Takayoshi Suzuki

doi:10.1002/jhet.1827

Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO₃] under mild conditions

Hossein Loghmani-Khouzani, Panteha Tamjidi, Iraj Mohammadpoor-Baltork, Marzieh Yaeghoobi, Noorsaadah Abd Rahman, Ahmad Reza Khosropour, Majid Moghadam, Shahram Tangestaninejad, Valiolah Mirkhani, Mohammad Hossein Habibi, Ayana Kashima, Takayoshi Suzuki

Research Institute for Interdisciplinary Science

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO₃] has been used as a catalyst that acts as an environmental friendly system.

Original language	English
Pages (from-to)	138-150
Number of pages	13
Journal	Journal of Heterocyclic Chemistry
Volume	51
Issue number	1
DOIs	https://doi.org/10.1002/jhet.1827
Publication status	Published - Jan 1 2014

ASJC Scopus subject areas

Organic Chemistry

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10.1002/jhet.1827

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Loghmani-Khouzani, H., Tamjidi, P., Mohammadpoor-Baltork, I., Yaeghoobi, M., Rahman, N. A., Khosropour, A. R., Moghadam, M., Tangestaninejad, S., Mirkhani, V., Habibi, M. H., Kashima, A., & Suzuki, T. (2014). Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO₃] under mild conditions. Journal of Heterocyclic Chemistry, 51(1), 138-150. https://doi.org/10.1002/jhet.1827

Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO₃] under mild conditions. / Loghmani-Khouzani, Hossein; Tamjidi, Panteha; Mohammadpoor-Baltork, Iraj; Yaeghoobi, Marzieh; Rahman, Noorsaadah Abd; Khosropour, Ahmad Reza; Moghadam, Majid; Tangestaninejad, Shahram; Mirkhani, Valiolah; Habibi, Mohammad Hossein; Kashima, Ayana; Suzuki, Takayoshi.

In: Journal of Heterocyclic Chemistry, Vol. 51, No. 1, 01.01.2014, p. 138-150.

Research output: Contribution to journal › Article › peer-review

Loghmani-Khouzani, H, Tamjidi, P, Mohammadpoor-Baltork, I, Yaeghoobi, M, Rahman, NA, Khosropour, AR, Moghadam, M, Tangestaninejad, S, Mirkhani, V, Habibi, MH, Kashima, A & Suzuki, T 2014, 'Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO₃] under mild conditions', Journal of Heterocyclic Chemistry, vol. 51, no. 1, pp. 138-150. https://doi.org/10.1002/jhet.1827

Loghmani-Khouzani, Hossein ; Tamjidi, Panteha ; Mohammadpoor-Baltork, Iraj ; Yaeghoobi, Marzieh ; Rahman, Noorsaadah Abd ; Khosropour, Ahmad Reza ; Moghadam, Majid ; Tangestaninejad, Shahram ; Mirkhani, Valiolah ; Habibi, Mohammad Hossein ; Kashima, Ayana ; Suzuki, Takayoshi. / Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO₃] under mild conditions. In: Journal of Heterocyclic Chemistry. 2014 ; Vol. 51, No. 1. pp. 138-150.

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abstract = "This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system.",

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AU - Mohammadpoor-Baltork, Iraj

AU - Yaeghoobi, Marzieh

AU - Rahman, Noorsaadah Abd

AU - Khosropour, Ahmad Reza

AU - Moghadam, Majid

AU - Tangestaninejad, Shahram

AU - Mirkhani, Valiolah

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