Effect of water on the magnesite–iron interaction, with implications for the fate of carbonates in the deep mantle

N. S. Martirosyan, A. Shatskiy, A. D. Chanyshev, K. D. Litasov, I. V. Podborodnikov, T. Yoshino

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    The subduction of carbonates beyond 250–300 km, where redox conditions favour the presence of metallic iron (Fe), will result in redox reactions with the Fe dispersed in the silicate rocks. Here, we studied the effect of water on the carbonate–Fe interaction in the hydromagnesite–Fe system at 6, 8 and 16 GPa and the peridotite–CO 2 –H 2 O–Fe system at 8 GPa, using a multianvil apparatus. In all of the studied samples, we observed the formation of magnesiowüstite, graphite and carbide. Additionally, in the peridotite–CO 2 –H 2 O–Fe system, magnesiowüstite reacted with pyroxenes, resulting in olivine enrichment. Kinetic calculations performed at 8 GPa showed that, at the pressure–temperature (P–T) parameters of the ‘hot’ ‘medium’ and ‘cold’ subduction, about 40, 12 and 4 vol% of carbonates, respectively, would be reduced in the hydrous system within 1 Myr, assuming direct contact with Fe. Based on the present results, it is suggested that carbonates will largely be consumed during the characteristic subduction time to the mantle transition zone by reaction with the reduced mantle in the presence of hydrous fluid.

    Original languageEnglish
    Pages (from-to)435-445
    Number of pages11
    JournalLITHOS
    Volume326-327
    DOIs
    Publication statusPublished - Feb 2019

    Keywords

    • Deep carbon cycle
    • High pressure
    • Hydrous fluid
    • Kinetics
    • Peridotite
    • Redox reaction

    ASJC Scopus subject areas

    • Geology
    • Geochemistry and Petrology

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