Effect of hydrogen chloride in coal combustion flue gas on the mercury removal performance of activated carbon from coal combustion flue gas

Toru Yamada, Yuki Yamaji, Eiji Sasaoka, Shengji Wu, Azhar Uddin

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

In this study, the effect of HCl on the Hg0 removal performance for coal combustion flue gas system using activated carbons prepared from fly ash and pitch and activated carbon derived from coconut shell (a commercial sample) was investigated. Mercury (Hg0) removal capacity of fly ash-pitch activated carbon was higher than that of coconut shell activated carbon in the absence of HCl, however fly ash-pitch activated carbon showed lower mercury adsorption performance compared to the coconut shell activated carbon in the presence of HCl. It is suggest that in the absence of HCl, surface H2SO4 was produced by the adsorption of SO2, O2 and H2O on the activated carbon which then reacted with Hg0 to produce HgSO4 and enhanced the mercury adsorption capacity of the activated carbons. The presence of HCl in the feed gas increased the Hg0 removal performance of the activated carbon sorbents many fold. However, the presence of SO2 has an adverse effect on the adsorption capacity of the activated carbons in the presence of HCl.

Original languageEnglish
Title of host publication23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development
Publication statusPublished - 2006
Event23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development - Pittsburgh, PA, United States
Duration: Sep 25 2006Sep 28 2006

Other

Other23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development
CountryUnited States
CityPittsburgh, PA
Period9/25/069/28/06

Fingerprint

hydrogen chlorides
flue gases
Coal combustion
activated carbon
Flue gases
coal
Activated carbon
Hydrogen
fly ash
Fly ash
Adsorption
adsorption
sorbents
Sorbents

ASJC Scopus subject areas

  • Energy Engineering and Power Technology
  • Condensed Matter Physics

Cite this

Yamada, T., Yamaji, Y., Sasaoka, E., Wu, S., & Uddin, A. (2006). Effect of hydrogen chloride in coal combustion flue gas on the mercury removal performance of activated carbon from coal combustion flue gas. In 23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development

Effect of hydrogen chloride in coal combustion flue gas on the mercury removal performance of activated carbon from coal combustion flue gas. / Yamada, Toru; Yamaji, Yuki; Sasaoka, Eiji; Wu, Shengji; Uddin, Azhar.

23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development. 2006.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Yamada, T, Yamaji, Y, Sasaoka, E, Wu, S & Uddin, A 2006, Effect of hydrogen chloride in coal combustion flue gas on the mercury removal performance of activated carbon from coal combustion flue gas. in 23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development. 23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development, Pittsburgh, PA, United States, 9/25/06.
Yamada T, Yamaji Y, Sasaoka E, Wu S, Uddin A. Effect of hydrogen chloride in coal combustion flue gas on the mercury removal performance of activated carbon from coal combustion flue gas. In 23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development. 2006
Yamada, Toru ; Yamaji, Yuki ; Sasaoka, Eiji ; Wu, Shengji ; Uddin, Azhar. / Effect of hydrogen chloride in coal combustion flue gas on the mercury removal performance of activated carbon from coal combustion flue gas. 23rd Annual International Pittsburgh Coal Conference, PCC - Coal-Energy, Environment and Sustainable Development. 2006.
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