Effect of heating rate on positive-temperature-coefficient-of-resistivity behavior of conductive composite thin films

S. Hirano, Akira Kishimoto

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A phenomenon was discovered that leads to the selective detection of abrupt increases in the temperature of conductive composite thin films consisting of conductive ceramic fillers and an insulating polymer matrix. Examining the heating rate dependence of the positive-temperature-coefficient-of-resistivity (PTCR) effect provided information about this intelligent phenomenon. The anomalous PTCR effect was observed above 0.3 °C min-1 for all the prepared films. However, the magnitude of the anomaly decreased when the heating rate decreased below 0.1 ° Cmin-1, and when the heating rate further decreased below 0.04 °C min-1, the anomalous resistivity-temperature relationship disappeared. The results suggest that these thin films can selectively detect abrupt increases in temperature, which could lead to an intelligent mechanism. Our results also suggest a PTCR mechanism, in which the expansion of crosslinked polymers in the thermodynamic nonequilibrium state essentially produces the anomaly.

Original languageEnglish
Pages (from-to)3742-3744
Number of pages3
JournalApplied Physics Letters
Volume73
Issue number25
DOIs
Publication statusPublished - 1998
Externally publishedYes

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electrical resistivity
heating
composite materials
coefficients
thin films
temperature
anomalies
nonequilibrium thermodynamics
polymers
fillers
ceramics
expansion
matrices

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

Cite this

Effect of heating rate on positive-temperature-coefficient-of-resistivity behavior of conductive composite thin films. / Hirano, S.; Kishimoto, Akira.

In: Applied Physics Letters, Vol. 73, No. 25, 1998, p. 3742-3744.

Research output: Contribution to journalArticle

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