Effect of applying voltage on photocatalytic destruction of 1,4-dioxane in aqueous system

Sayaka Yanagida; Akira Nakajima; Yoshikazu Kameshima; Kiyoshi Okada

doi:10.1016/j.catcom.2006.05.016

Effect of applying voltage on photocatalytic destruction of 1,4-dioxane in aqueous system

Sayaka Yanagida, Akira Nakajima, Yoshikazu Kameshima, Kiyoshi Okada

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

In the current work, we prepared a TiO₂ coating on stainless mesh using electrophoretic deposition (EPD), and applied voltage to a stainless mesh to examine the synergy effect on photocatalysis of both 1,4-dioxane and ethylene glycol diformate (EGDF), a main intermediate of the photocatalysis of 1,4-dioxane. The photocatalytic decomposition rate of 1,4-dioxane depends on applying voltage under diffusion-limited reaction conditions. Ethylene glycol diformate and 1,4-dioxane exhibited inverse voltage dependence. Voltage swing provides high-efficiency photocatalysis of 1,4-dioxane while suppressing EGDF formation. This method will be effective for a photocatalysis system containing several chemicals, each with different voltage dependence.

Original language	English
Pages (from-to)	1042-1046
Number of pages	5
Journal	Catalysis Communications
Volume	7
Issue number	12
DOIs	https://doi.org/10.1016/j.catcom.2006.05.016
Publication status	Published - Dec 2006
Externally published	Yes

Keywords

1,4-Dioxane
Electrophoretic deposition
Photocatalyst
TiO
Voltage

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Process Chemistry and Technology

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title = "Effect of applying voltage on photocatalytic destruction of 1,4-dioxane in aqueous system",

abstract = "In the current work, we prepared a TiO2 coating on stainless mesh using electrophoretic deposition (EPD), and applied voltage to a stainless mesh to examine the synergy effect on photocatalysis of both 1,4-dioxane and ethylene glycol diformate (EGDF), a main intermediate of the photocatalysis of 1,4-dioxane. The photocatalytic decomposition rate of 1,4-dioxane depends on applying voltage under diffusion-limited reaction conditions. Ethylene glycol diformate and 1,4-dioxane exhibited inverse voltage dependence. Voltage swing provides high-efficiency photocatalysis of 1,4-dioxane while suppressing EGDF formation. This method will be effective for a photocatalysis system containing several chemicals, each with different voltage dependence.",

keywords = "1,4-Dioxane, Electrophoretic deposition, Photocatalyst, TiO, Voltage",

author = "Sayaka Yanagida and Akira Nakajima and Yoshikazu Kameshima and Kiyoshi Okada",

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T1 - Effect of applying voltage on photocatalytic destruction of 1,4-dioxane in aqueous system

AU - Yanagida, Sayaka

AU - Nakajima, Akira

AU - Kameshima, Yoshikazu

AU - Okada, Kiyoshi

PY - 2006/12

Y1 - 2006/12

N2 - In the current work, we prepared a TiO2 coating on stainless mesh using electrophoretic deposition (EPD), and applied voltage to a stainless mesh to examine the synergy effect on photocatalysis of both 1,4-dioxane and ethylene glycol diformate (EGDF), a main intermediate of the photocatalysis of 1,4-dioxane. The photocatalytic decomposition rate of 1,4-dioxane depends on applying voltage under diffusion-limited reaction conditions. Ethylene glycol diformate and 1,4-dioxane exhibited inverse voltage dependence. Voltage swing provides high-efficiency photocatalysis of 1,4-dioxane while suppressing EGDF formation. This method will be effective for a photocatalysis system containing several chemicals, each with different voltage dependence.

AB - In the current work, we prepared a TiO2 coating on stainless mesh using electrophoretic deposition (EPD), and applied voltage to a stainless mesh to examine the synergy effect on photocatalysis of both 1,4-dioxane and ethylene glycol diformate (EGDF), a main intermediate of the photocatalysis of 1,4-dioxane. The photocatalytic decomposition rate of 1,4-dioxane depends on applying voltage under diffusion-limited reaction conditions. Ethylene glycol diformate and 1,4-dioxane exhibited inverse voltage dependence. Voltage swing provides high-efficiency photocatalysis of 1,4-dioxane while suppressing EGDF formation. This method will be effective for a photocatalysis system containing several chemicals, each with different voltage dependence.

KW - 1,4-Dioxane

KW - Electrophoretic deposition

KW - Photocatalyst

KW - TiO

KW - Voltage

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Effect of applying voltage on photocatalytic destruction of 1,4-dioxane in aqueous system

Abstract

Keywords

ASJC Scopus subject areas

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