Effect of alloying element content on ion-nitriding behavior of Fe-Ti alloys

Jun Takada, Yuusuke Oizumi, Hiroshi Miyamura, Hideyuki Kuwahara, Shiomi Kikuchi

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16 Citations (Scopus)

Abstract

The ion-nitriding behavior of iron alloys with a titanium content of between 1.07 and 2.58 wt.% was investigated in the α-phase region. The behavior was found to be analogous to the internal oxidation behavior of iron alloys: An internal-nitriding layer, where small TiN precipitates are dispersed, as well as a very thin surface layer of γ′-Fe4N were formed. A parabolic rate law holds for growth of the internal-nitriding layer. The kinetics of growth of the internalnitriding layer is discussed according to the rate equation of internal-oxidation, giving the diffusion coefficient of nitrogen, DNapp, in the layer. The measured DNapp decreases as the volume fraction of TiN, f, increases, indicating that the diffusion of nitrogen is apparently inhibited by the existence of TiN precipitates. Furthermore, the diffusion coefficient of nitrogen in α-iron was evaluated by extrapolating DNapp to f=0, being in good agreement with that reported previously. The f-dependence of DNapp is discussed in terms of the effective area for diffusion of nitrogen in α-iron.

Original languageEnglish
Pages (from-to)19-31
Number of pages13
JournalOxidation of Metals
Volume26
Issue number1-2
DOIs
Publication statusPublished - Aug 1 1986

Keywords

  • Fe-Ti alloys
  • TiN, y′-FeN
  • diffusion coefficient of nitrogen
  • hardness
  • ion-nitriding

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry

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    Takada, J., Oizumi, Y., Miyamura, H., Kuwahara, H., & Kikuchi, S. (1986). Effect of alloying element content on ion-nitriding behavior of Fe-Ti alloys. Oxidation of Metals, 26(1-2), 19-31. https://doi.org/10.1007/BF00664271