Abstract
1-Sulfonyl-1,2,3-triazoles undergo a Doyle-Kirmse reaction upon treatment with allylic sulfides in the presence of a rhodium(II) catalyst to afford α-allyl-α-sulfanylimines. Terminal alkynes are regioselectively multifunctionalized by the introduction of C-N, C-S, and C-C bonds through a one-pot sequence consisting of a [3 + 2] dipolar cycloaddition reaction with azide and subsequent Doyle-Kirmse reaction.
Original language | English |
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Pages (from-to) | 1308-1310 |
Number of pages | 3 |
Journal | Chemistry Letters |
Volume | 42 |
Issue number | 10 |
DOIs | |
Publication status | Published - 2013 |
Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)